Porous metal oxide microspheres from ion exchange resin

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• 作者：S. Picart ; P. Parant ; M. Caisso ; E. Remy…
• 刊名：The European Physical Journal - Special Topics
• 出版年：2015
• 出版时间：July 2015
• 年：2015
• 卷：224
• 期：9
• 页码：1675-1687
• 全文大小：1,427 KB
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• 作者单位：S. Picart (1)
  P. Parant (1)
  M. Caisso (1) (2)
  E. Remy (1)
  H. Mokhtari (1)
  I. Jobelin (1)
  J.P. Bayle (2)
  C.L. Martin (3)
  P. Blanchart (4)
  A. Ayral (5)
  T. Delahaye (1)
  
  1. CEA, Nuclear Energy Division, Radiochemistry and Processes Department, 30207, Bagnols-sur-Cèze, France
  2. CEA, Nuclear Energy Division, Fuel Cycle Technology Department, 30207, Bagnols-sur-Cèze, France
  3. Univ. Grenoble Alpes, CNRS, SIMAP, 38000, Grenoble, France
  4. Heterogeneous Materials Research Group, Centre Européen de la Céramique, 87068, Limoges, France
  5. Institut Européen des Membranes, CNRS-ENSCM-UM2, CC47, University Montpellier 2, 34095, Montpellier, France
  
• 刊物类别：Physics and Astronomy
• 刊物主题：Physics
  Condensed Matter
  Materials Science
  Atoms, Molecules, Clusters and Plasmas
  Electromagnetism, Optics and Lasers
  Measurement Science and Instrumentation
  Mechanics, Fluids and Thermodynamics
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1951-6401

文摘

This study is devoted to the synthesis and the characterization of porous metal oxide microsphere from metal loaded ion exchange resin. Their application concerns the fabrication of uranium-americium oxide pellets using the powder-free process called Calcined Resin Microsphere Pelletization (CRMP). Those mixed oxide ceramics are one of the materials envisaged for americium transmutation in sodium fast neutron reactors. The advantage of such microsphere precursor compared to classical oxide powder is the diminution of the risk of fine dissemination which can be critical for the handling of highly radioactive powders such as americium based oxides and the improvement of flowability for the filling of compaction chamber. Those millimetric oxide microspheres incorporating uranium and americium were synthesized and characterizations showed a very porous microstructure very brittle in nature which occurred to be adapted to shaping by compaction. Studies allowed to determine an optimal heat treatment with calcination temperature comprised between 700-00?°C and temperature rate lower than 2?°C/min. Oxide Precursors were die-pressed into pellets and then sintered under air to form regular ceramic pellets of 95% of theoretical density (TD) and of homogeneous microstructure. This study validated thus the scientific feasibility of the CRMP process to prepare bearing americium target in a powder free manner.