Evaluation of the Physical–Chemical Characteristics of Wastewater After Disinfection with Peracetic Acid

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• 作者：Grasiele Soares Cavallini ; Sandro Xavier de Campos…
• 关键词：Peracetic acids ; Physical–chemical characteristics ; Degradation kinetics ; By ; products
• 刊名：Water, Air, and Soil Pollution
• 出版年：2013
• 出版时间：October 2013
• 年：2013
• 卷：224
• 期：10
• 全文大小：349KB
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• 作者单位：Grasiele Soares Cavallini (1)
  Sandro Xavier de Campos (2)
  Jeanette Beber de Souza (3)
  Carlos Magno de Sousa Vidal (3)
  
  1. Laboratory of Environmental Sanitation and Water Quality, State University of the Centro-Oeste (UNICENTRO), PR 153 km 7, Riozinho, Irati, Parana, 84500-000, Brazil
  2. State University of Ponta Grossa—UEPG, Post-Graduation Program in Applied Chemistry, Avenue General Carlos Cavalcanti, 4748, Uvaranas, Ponta Grossa 84030-900, Parana, Brazil
  3. Department of Environmental Engineering, UNICENTRO, PR 153 km 7, Riozinho, Irati, Parana, 84500-000, Brazil
  
• ISSN：1573-2932

文摘

The use of peracetic acid (PAA) in the disinfection of sanitary effluents has been proposed by various authors. However, there are still doubts about its influence on the physical–chemical characteristics of the effluent after application. In the present study, it was observed that the composition of PAA leads to an increase in organic material, resulting in an increase of approximately 20?mg/L in the chemical oxygen demand of the effluent for every 10?mg/L of PAA applied. According to the kinetic tests, the degradation of PAA in the effluent was represented by a first-order reaction and its half-life in the effluent was estimated at 79?min. The formation of by-products resulting from degradation of PAA in the effluent was evaluated by considering by-products already detected by other authors in disinfection trials, these being nonanal, decanal, chlorophenols, and 1-methoxy-4-methylbenzene, which were not observed in the effluent being studied after application of PAA at a dosage of 10?mg/L.