Effect of Nonionic Surfactant on the Micro-Emulsifying Water in Silicone Media

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• 作者：Liujun Pei ; Ping Wu ; Juanjuan Liu ; Jiping Wang
• 关键词：Reverse micro ; emulsion ; Silicone media ; Nonionic surfactant
• 刊名：Journal of Surfactants and Detergents
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：20
• 期：1
• 页码：247-254
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Industrial Chemistry/Chemical Engineering; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution; Surfaces and Interfaces, Thin Films; Polymer Sciences; Physical Chem
• 出版者：Springer Berlin Heidelberg
• ISSN：1558-9293
• 卷排序：20

文摘

Reverse micro-emulsion dyeing technology shows a high dye uptake and fixation rate, and effectively decreases the amount of waste water in the textile industry. However, the influence of surfactants and co-surfactants on micro-emulsifying water in reverse micro-emulsions has not been investigated. In this study, the micro-emulsifying mechanism in silicone media and the influence of nonionic surfactants and co-surfactants on micro-emulsifying water have been investigated. The results show that a large amount of water can be emulsified using alcohol-polyoxyethylene ethers, especially under 3–5 ethylene oxide groups in molecular structure. As co-surfactant, alcohol which contains 4–9 carbon chains could spontaneously form reverse micro-emulsions in silicone media. The effects of solution pH and ionic strength on the amount of emulsified water were also evaluated. The results show that a large amount of water could be emulsified in silicone media at solution pH 2–9. Meanwhile, the amount of emulsified water decreased with increasing ionic strength. Thus, the optimum conditions for water emulsification are low ionic strength and pH between 2 and 9.