Optical determination of hydrogen peroxide by exploiting the peroxidase-like activity of AgVO3 nanobelts
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  • 作者:Zhenbo Xiang ; Yi Wang ; Peng Ju ; Dun Zhang
  • 关键词:Silver vanadate ; X ; ray diffraction ; Scanning electron microscopy ; Transmission electron microscopy ; Kinetic assay ; Peroxidase mimic ; Photometric determination
  • 刊名:Microchimica Acta
  • 出版年:2016
  • 出版时间:January 2016
  • 年:2016
  • 卷:183
  • 期:1
  • 页码:457-463
  • 全文大小:2,156 KB
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  • 作者单位:Zhenbo Xiang (1) (2)
    Yi Wang (1)
    Peng Ju (1) (2)
    Dun Zhang (1)

    1. Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, 7 Nanhai Road, Qingdao, 266071, China
    2. University of the Chinese Academy of Sciences, 19 (Jia) Yuquan Road, Beijing, 100039, China
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Analytical Chemistry
    Inorganic Chemistry
    Physical Chemistry
    Characterization and Evaluation Materials
    Monitoring, Environmental Analysis and Environmental Ecotoxicology
  • 出版者:Springer Wien
  • ISSN:1436-5073
文摘
AgVO3 nanobelts (typically 0.5 to 5 μm in length; 100 nm in width) are demonstrated for the first time to possess intrinsic peroxidase-like activity. The substrate 3,3′,5,5′-tetramethylbenzidine is converted to a blue dye (with an absorbance maximum at 652 nm) in the presence of H2O2. Kinetic analysis indicates that the catalytic reaction follows a ping-pong mechanism. Moreover, a possible photocatalytic mechanism is proposed based on active species trapping experiments, demonstrating that hydroxy radicals play major roles in this system. This feature of the nanobelts is used for quantitative kinetic determination of H2O2. The assay has a 5 μM detection limit and a detection range from 0.075 to 0.5 mM. Other attractive features include a good chemical stability and high specificity of the nanobelts, simplicity of the assay, and the good reproducibility of the synthesis of the material.

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