Microwave-Assisted Polymer Modifications

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• 关键词：Carbon nanomaterials ; Microwave ; assisted synthesis ; Poly(ethylene imine) ; Polymer modification ; Polysaccharide ; Post ; polymerization modification
• 刊名：Advances in Polymer Science
• 出版年：2016
• 出版时间：2016
• 年：2016
• 卷：274
• 期：1
• 页码：209-240
• 全文大小：2,927 KB
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• 作者单位：Christoph Englert (22) (23)
  Almut M. Schwenke (22) (23)
  Stephanie Hoeppener (22) (23)
  Christine Weber (22) (23)
  Ulrich S. Schubert (22) (23)
  
  22. Laboratory for Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstrasse 10, 07743, Jena, Germany
  23. Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, 07743, Jena, Germany
  
• 丛书名：Microwave-assisted Polymer Synthesis
• ISBN：978-3-319-42241-1
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1436-5030
• 卷排序：274

文摘

Modern microwave synthesizers allow a detailed adjustment and control of temperature and power, such that many polymer modification reactions are performed nowadays using established synthesis protocols. This chapter provides a broad overview of post-polymerization modification reactions where these advantages are exploited for functionalization of synthetic and natural polymers. Selected examples are discussed in detail to demonstrate the versatility of the technique but also to address the challenges of screening approaches often applied to identify the optimum reaction conditions. While microwave synthesizers are regarded as efficient heating devices in the field of synthetic chemistry, selective heating of, for example, conjugated polymers has opened non-standard opportunities for the development of novel nanomaterials.