Synthesis, characterization, and application of poly(4-vinylpyridinium butane sulfonic acid) hydrogen sulfate as a novel poly(ionic liquid) and heterogeneous solid acid catalyst for the preparation of 1,8-dioxo-octahydroxanthenes

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• 作者：Ali Reza Kiasat (1)
  Arash Mouradzadegun (1)
  Seyyed Jafar Saghanezhad (1)
  
  1. Chemistry Department ; College of Science ; Shahid Chamran University ; P. O. Box 61357-4-3169 ; Ahvaz ; Iran
  
• 关键词：Solvent ; free ; Dimedone ; Poly(ionic liquid) ; Poly(4 ; vinylpyridine) ; Heterogeneous catalyst
• 刊名：Research on Chemical Intermediates
• 出版年：2015
• 出版时间：January 2015
• 年：2015
• 卷：41
• 期：1
• 页码：319-326
• 全文大小：761 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

Poly(4-vinylpyridinium butane sulfonic acid) hydrogen sulfate, P(4VPBSA)HSO4, a novel polymeric acidic catalyst, was easily prepared by reaction of cross-linked poly(4-vinylpyridine) with 1,4-butane sultone and further acidification of the catalyst with sulfuric acid. The catalyst was studied by FT-IR spectroscopy, scanning electron microscopy, and thermogravimetric analysis. The poly(ionic liquid) catalyst was shown to be an efficient dual acidic catalyst for one-pot preparation of 1,8-dioxo-octahydroxanthenes under solvent-free conditions. Reusability of the catalyst, easy work-up, eco-friendly reaction conditions, short reaction times, and high yields are some advantages of this procedure.