Chemical polymerization of aniline in the presence of mixtures of polymeric sulfonic acids

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• 作者：O. D. Omel’chenko (19341)
  O. L. Gribkova (19341)
  A. A. Nekrasov (19341)
  V. F. Ivanov (19341)
  V. V. Kravchenko (29341)
  A. V. Vannikov (19341)
  V. A. Tverskoi (29341)
  
• 刊名：Polymer Science Series B
• 出版年：2013
• 出版时间：4 - March 2013
• 年：2013
• 卷：55
• 期：3
• 页码：187-194
• 全文大小：238KB
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• 作者单位：O. D. Omel’chenko (19341)
  O. L. Gribkova (19341)
  A. A. Nekrasov (19341)
  V. F. Ivanov (19341)
  V. V. Kravchenko (29341)
  A. V. Vannikov (19341)
  V. A. Tverskoi (29341)
  
  19341. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia
  29341. Moscow University of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia
  
• ISSN：1555-6123

文摘

The template polymerization of aniline in the presence of polymeric sulfonic acids of various structures and their mixtures is studied. In the latter case, the dominant effect of a polyacid on the kinetics of aniline polymerization and the electronic structure of the resulting polyaniline complex is observed. As shown by viscometry measurements and IR studies, the intermolecular interaction between polyacids in their mixtures that leads to a change in the conformation of a flexible-chain polyacid is responsible for the dominant effect of a rigid-chain polyacid. The spectral and electrical properties of polyaniline-based interpolymer complexes are examined.