Synthesis of superhydrophobic fluorinated polystyrene microspheres via distillation precipitation polymerization

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• 作者：Dongwei Zhang ; Jiawei Liu ; Tuanwei Liu ; Xinlin Yang
• 关键词：Fluorinated polymer microsphere ; Superhydrophobic ; Distillation precipitation polymerization
• 刊名：Colloid & Polymer Science
• 出版年：2015
• 出版时间：June 2015
• 年：2015
• 卷：293
• 期：6
• 页码：1799-1807
• 全文大小：1,651 KB
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• 作者单位：Dongwei Zhang (1)
  Jiawei Liu (1)
  Tuanwei Liu (1)
  Xinlin Yang (1)
  
  1. Key Laboratory of Functional Polymer Materials, Ministry of Education, Institute of Polymer Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin, 300071, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Physical Chemistry
  Soft Matter and Complex Fluids
  Characterization and Evaluation Materials
  Food Science
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1435-1536

文摘

Superhydrophobic fluorinated polystyrene microspheres were prepared by distillation precipitation polymerization of 4-fluorostyrene (FSt), styrene (St), with divinylbenzene (DVB) as cross-linker in acetonitrile in the absence of any stabilizer. Both the fluorine contents and sizes of the polymeric microspheres were tuned via altering the feed ratio of the fluorinated monomers for polymerization. The films via casting the suspension with fluorinated microspheres exhibited a superhydrophobic behavior with contact angles larger than 150°. The resultant microspheres were characterized by transmission electron microscopy (TEM), Fourier-transform infrared spectrometry (FTIR), X-ray photoelectron spectroscopy (XPS), ion chromatography, and contact angle system.