Synthesis, thermal degradation and dielectric properties of poly[2-hydroxy,3-(1-naphthyloxy)propyl methacrylate]
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- 作者：Fatih Biryan ; Kadir Demirelli ; Gülben Torğut ; Güzin Pıhtılı
- 关键词：NOPMA synthesis ; Thermal degradation ; Dielectric properties ; Polymerization
- 刊名：Polymer Bulletin
- 出版年：2017
- 出版时间：February 2017
- 年：2017
- 卷：74
- 期：2
- 页码：583-602
- 全文大小：1381KB
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Polymer Sciences; Soft and Granular Matter, Complex Fluids and Microfluidics; Characterization and Evaluation of Materials; Physical Chemistry;
- 出版者：Springer Berlin Heidelberg
- ISSN：1436-2449
- 卷排序：74
文摘
2-Hydroxy-3-(1-naphthyloxy)propyl methacrylate (NOPMA) monomer was synthesized from reaction of 2-[(2-naphthyloxy)methyl]oxirane with methacrylic acid in the presence of pyridine. The polymerization of NOPMA was carried out by free radical polymerization method in the presence of AIBN at 60 °C. The structure of monomer and polymer was characterized by 1H-NMR, 13C-NMR and FT-IR spectroscopy techniques. The glass transition temperature and average-molecular weights of poly(NOPMA) were measured using differential scanning calorimetry and gel permeation chromatography, respectively. The thermal degradation behavior of poly(NOPMA) has been investigated by FT-IR studies of the partially degraded polymer and thermogravimetry. The cold ring fractions (CRFs) were collected at two different temperatures, initially fraction-1 (CRF1) is from room temperature to 320 °C, and the other fraction-2 (CRF2) is from 320 to 500 °C. The volatile products of the degradation were trapped at −195 °C (in liquid nitrogen). All the fractions were characterized by FT-IR, 1H and 13C-NMR spectroscopic techniques, and the cold ring fractions (CRFs) were also characterized by GC–MS. For the degradation of polymer, the major compound between products of CRFs is α-naphthol. The GC–MS, FT-IR and NMR data showed that depolymerization corresponding to monomer was not prominent below 320 °C in the thermal degradation of poly(NOPMA). The mode of thermal degradation containing formation of the major products was identified. The dielectric permittivity (ε′), the loss factor (ε″) and conductivity (σac) were measured using a dielectric analyzer in the frequency range of 50 Hz to 20 kHz.