Hydrogeochemical processes of fluoride enrichment in Chimakurthy pluton, Prakasam District, Andhra Pradesh, India

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• 作者：A. G. S. Reddy ; D. V. Reddy ; M. Sudheer Kumar
• 关键词：Groundwater ; Fluoride ; Na+ ; Bicarbonate ; Gabbro ; Silicate weathering ; Water types
• 刊名：Environmental Earth Sciences
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：75
• 期：8
• 全文大小：1,552 KB
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• 作者单位：A. G. S. Reddy (1)
  D. V. Reddy (2)
  M. Sudheer Kumar (3)
  
  1. RGNGWT&RI, Raipur, CG, India
  2. CSIR-NGRI, Hyderabad, India
  3. CGWB, SR, Hyderabad, TS, India
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：None Assigned
• 出版者：Springer Berlin Heidelberg
• ISSN：1866-6299

文摘

Thirty-six groundwater samples were collected from Chimakurthy area, Prakasam District, Andhra Pradesh. On hydrogeochemical evaluation, it was found to be contaminated. Based on fluoride concentration, the samples were segregated into Group A, Group B, and Group C. Fluoride concentration varies from 0.23 to 9.84 mg/l, with the mean value of 2.01 mg/l; 44 % of the tested samples had F− > 1.50 mg/l. Apart from F−, the water was contaminated with NO₃ − and Cl− implying both geogenic and anthropogenic pollution of the aquifer. Ionic dominance pattern was unique in samples with low, moderate to high F− concentrations. Na+ and HCO₃ − were progressively increasing along with F− from Group A to C, whereas Ca2+ and Mg2+ were depleting. Groundwater facies were unique among different group samples especially in end members with low and high F− concentration suggesting that F− dissolution was strongly influenced by the chemical nature of solution. Na+/Cl− molar ratio was >1, whereas Na+ + K+:Tz+ and Ca2+ + Mg2+:Tz+ ratios were <1 in all samples indicating that Na+ was released from silicate weathering process. It also confirms that F− was contributed from lithogenic sources of aquifer material. Mean molecular ratios of <1 for Ca2+:Mg2+ in Group B samples and 1–1.2 in Groups A and C support that the Ca2+ and Mg2+ were added into aquatic medium by calcite and dolomite dissolution. Contradictory distribution of F− in north (low) and south (high) indicates that availability of F− minerals in aquifer matrix influenced the rate of F− absorption in accompanying water. Variation in F− concentration in groundwater of the core area (south) supports the hypothesis of aquatic chemistry acting as catalyst in F− dissolution into formation waters even though the aquifer was enriched with F− minerals. Very high F− in groundwater in the contact zone of country rock and plutonic intrusive indicates that F− mineralization occurred under geothermal conditions. The fracture network in disturbed and fragile contact zone has facilitated development of potential aquifers and enhancement in F− concentration.