Poisoning Deactivation of Mesoporous Titanosilicate-Supported WO3 During Metathesis of Butene to Propene

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• 作者：Derun Hua ; Shengli Chen ; Zheng Zhou ; Xinning Lu ; Jian Li
• 关键词：Deactivation ; Metathesis ; Poisoning
• 刊名：Catalysis Surveys from Japan
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：20
• 期：1
• 页码：53-58
• 全文大小：725 KB
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• 作者单位：Derun Hua (1) (2)
  Shengli Chen (2)
  Zheng Zhou (3)
  Xinning Lu (1)
  Jian Li (1)
  
  1. College of Chemistry and Chemical Engineering, Gannan Normal University, Jiangxi, 341000, China
  2. State Key Laboratory of Heavy Oil, College of Chemical Science and Engineering, China University of Petroleum, Beijing, 102249, People’s Republic of China
  3. Natural Gas Processing Plant of SINOPEC Zhongyuan Oilfield Branch, Puyang, 457001, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  
• 出版者：Springer Netherlands
• ISSN：1574-9266

文摘

Deactivation by poisoning is studied in the metathesis of 2-butene to propene on mesoporous titanosilicate-supported WO₃ (WO₃/MTS–9), for which we focus on the effect of polar organic oxygenates on the activity of the catalyst. It is found that deactivation is strongly influenced by these oxygenates in feedstock, and the rate of deactivation increases with the increase of the polarity of the organic oxygenates. The deactivation by poisoning is reversible. The deactivation catalyst can be recovered by treatment in a nitrogen atmosphere at a high temperature. Keywords Deactivation Metathesis Poisoning