Nanocomposites of novolac type phenolic resins and organoclays: The effects of the resin molecular weight and the amine salt structure on the morphology and the mechanical properties of the composites

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• 作者：Sang Chul Roh (1)
  Hyuk Joong Kwan (1)
  Chang Keun Kim (1) ckkim@cau.ac.kr
• 关键词：novolac phenolic resin &#8211 ; organoclays &#8211 ; nanocomposite &#8211 ; molecular weight of resin &#8211 ; resin coated sand &#8211 ; mechanical properties
• 刊名：Macromolecular Research
• 出版年：2012
• 出版时间：May 2012
• 年：2012
• 卷：20
• 期：5
• 页码：496-502
• 全文大小：731.6 KB
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• 作者单位：1. School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul, 156-756 Korea
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Polymer Sciences
  Characterization and Evaluation of Materials
  Soft and Granular Matter, Complex Fluids and Microfluidics
  Nanochemistry
  Nanotec
  
• 出版者：The Polymer Society of Korea, co-published with Springer
• ISSN：2092-7673

文摘

Nanocomposites of novolac-type phenolic resins having various molecular weights with a series of organoclays containing organic amine salts were prepared by melt processing. The effects of the molecular weight of novolac resin and the amine structure of organoclay on composite morphology and physical properties were examined. Composites containing organoclay exhibited the intercalated state with shifts in gallery spacing regardless of the molecular weight of novolac resin. The extent of silicate platelet intercalation increased as molecular weight of novolac resin increased and the number of long alkyl tails decreased from two to one. Novolac resin/organoclay composites cured with hexamethylenetetramine (HMTA) always exhibited better flexural and Izod impact strengths than the novolac resin cured with HMTA when the molecular weight of novolac resin was fixed. Among the nanocomposites prepared here using organoclays, those with higher platelet intercalation generally showed better flexural and Izod impact strengths. However, resin-coated sands prepared from organoclay containing one long alkyl tail exhibited only better flexural strength than that prepared from novolac resin.