Interrelation between the crystallinity of polysaccharides and water absorption

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• 作者：A. N. Prusov (1)
  S. M. Prusova (1)
  M. V. Radugin (1)
  A. G. Zakharov (1)
  
• 关键词：calorimetric measurements ; interaction enthalpy ; crystallinity ; maximum sorption
• 刊名：Russian Journal of Physical Chemistry A, Focus on Chemistry
• 出版年：2014
• 出版时间：May 2014
• 年：2014
• 卷：88
• 期：5
• 页码：813-818
• 全文大小：179 KB
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• 作者单位：A. N. Prusov (1)
  S. M. Prusova (1)
  M. V. Radugin (1)
  A. G. Zakharov (1)
  
  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, 153045, Russia
  
• ISSN：1531-863X

文摘

The maximum sorption of water and its vapors is calculated using experimental data from calorimetric and effusion studies of flax, wood, and cotton cellulose. X-day diffraction is used to determine the crystallinity of cellulose samples. The equations relating crystallinity (X) with maximum sorption and the enthalpy of interaction between cellulose and water are presented. Experimental results and the literature data on water sorption by chitin, chitosan and other polysaccharides show that our equations for calculating crystallinity are correct.