Synthesis, application, and flame-retardant mechanism of a novel phosphorus-containing plasticizer based on castor oil for polyvinyl chloride

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• 作者：Puyou Jia ; Meng Zhang ; Lihong Hu ; Caiying Bo…
• 关键词：Castor oil ; Plasticizer ; Flame ; retardant mechanism ; Polyvinyl chloride
• 刊名：Journal of Thermal Analysis and Calorimetry
• 出版年：2015
• 出版时间：June 2015
• 年：2015
• 卷：120
• 期：3
• 页码：1731-1740
• 全文大小：1,307 KB
• 参考文献：1.Silva MAD, Vieira MGA, Ma?umoto ACG, Beppu MM. Polyvinylchloride (PVC) and natural rubber films plasticized with a natural polymeric plasticizer obtained through polyesterification of rice fatty acid. Polym Test. 2011;30(5):478-4.View Article
  2.Saeki Y, Emura T. Technical progresses for PVC production. Prog Polym Sci. 2002;27:2055-31.View Article
  3.Lardjane N, Belhaneche-Bensemra N, Massardier V. Migration of new bio-based additives from rigid and plasticized PVC stabilized with epoxidized sunflower oil in soil. J Polym Res. 2013;20:209-9.View Article
  4.Sun T, Thom R. The effect of epoxidized safflower oil on the properties of polyvinyl chloride films. J Elastom Plast. 2010;42(2):129-7.View Article
  5.Palacios OYS, Narvaez Rincon PC, Jean-Pierre Corriou C, Pardo MC, Fonteix C. Low-molecular-weight glycerol esters as plasticizers for Poly(vinyl chloride). J Vin Add Tech. 2014;20(2):65-1.View Article
  6.Sander MM, Nicolau A, Guzatto R, Samios D. Plasticiser effect of oleic acid polyester on polyethylene and polypropylene. Polym Test. 2012;31(8):1077-2.View Article
  7.Greco A, Brunetti D, Renna G, Mele G, Maffezzoli A. Plasticizer for poly(vinyl chloride) from cardanol as a renewable resource material. Polymer Degrad Stab. 2010;95(11):2169-4.View Article
  8.Bueno-Ferrer C, Garrigós MC, Jiménez A. Characterization and thermal stability of poly(vinyl chloride) plasticized with epoxidized soybean oil for food packaging. Polymer Degrad Stab. 2012;95:2207-2.View Article
  9.Karmalm P, Hjertberg T, Jansson A, Dahl R. Thermal stability of poly(vinyl chloride) with eposidised soybean oil as primary plasticizer. Polymer Degrad Stab. 2009;94:2275-1.View Article
  10.Liu CG, Jun L, Wen L, Zhou YH. Development of biobased unsaturated polyester resin containing highly functionalized castor oil. Ind Crop Prod. 2014;52:329-7.View Article
  11.Zhang LQ, Zhang M, Zhou YH, Hu LH. The study of mechanical behavior and flame retardancy of castor oil phosphate-based rigid polyurethane foam composites containing expanded graphite and triethyl phosphate. Polymer Degrad Stab. 2013;98:2784-4.View Article
  12.Zhang LQ, Zhang M, Hu LH, Zhou YH. Synthesis of rigid polyurethane foams with castor oil-based flame retardant polyols. Ind Crop Prod. 2014;52:380-.View Article
  13.Yao Q, Wilkie CA. Thermal degradation of PVC in the presence of polystyrene. J Vinyl Addit Technol. 2001;7(1):26-6.View Article
  14.Soudais Y, Moga L, Blazek J, Lemort F. Coupled DTA-TGA-FT-IR investigation of pyrolytic decomposition of EVA, PVC and cellulose. J Anal Appl Pyrolysis. 2007;78(1):45-7.View Article
  15.Pan LL, Li GY, Su YC, Lian JS. Fire retardant mechanism analysis between ammonium polyphosphate and triphenyl phosphate in unsaturated polyester resin. Polym Degrad Stab. 2012;97:1801-.View Article
  16.Ying-Ling L, Yie-Chan C, Tsung-Yu C. Phosphorus-containing polyaryloxydiphenylsilanes with high flame retardance arising from a phosphorus–silicon synergistic effect. Polym Int. 2003;52:1256-1.View Article
  17.Shibin N, Chao P, Shujie Y. Thermal and flame retardant properties of a novel intumescent flame retardant polypropylene composites. J Thermal Anal Calorim. 2012;113:865-1.
  
• 作者单位：Puyou Jia (1)
  Meng Zhang (1) (2)
  Lihong Hu (1) (2)
  Caiying Bo (1)
  Yong-hong Zhou (1)
  
  1. Institute of Chemical Industry of Forest Products, Chinese Academy of Forest (CAF), Nanjing, 210042, People’s Republic of China
  2. Institute of New Technology of Forestry, Chinese Academy of Forest (CAF), Beijing, 100091, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Sciences
  Polymer Sciences
  Physical Chemistry
  Inorganic Chemistry
  Measurement Science and Instrumentation
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1572-8943

文摘

The objective of this study was to synthesize a novel flame-retardant plasticizer (PPC) for PVC using castor oil and to investigate the retardant mechanism of PVC blend plasticized with PPC. The chemical structure of PPC was characterized with FT-IR, 31P NMR, and 1H NMR. The melting behavior, thermal property, flame-retardant performance, flame-retardant mechanism, and mechanical property of PVC plasticized with PPC were systematically studied. The results showed that when the PPC content increased from 0 to 20?g in PVC blend, the torque increased from 10.6 to 15.9?N?m, and the glass transition temperature increased from 26.5 to 52.6?°C. Leaching tests indicated that PPC had a higher migration resistance than DOP. TG indicated that PPC could improve the thermal stability under 350?°C, and the LOI tests indicated that the LOI value of PVC blends cooperated with PPC increased from 26.6 to 32.4?%. The SEM and flame-retardant performance indicated that PPC was put into effect by promoting PVC carbonization and forming a consolidated and thick flame-retardant coating quickly, which is effective to prohibit the heat flux and air incursion. PPC could improve the flame-retardant performance of PVC blends and keep the mechanical properties unchanged comparing with DOP.