Highly efficient organic ultraviolet photodetectors based on excellent Cu (I) complexes
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  • 作者:C. -B. Liu (1) (3)
    B. Su (2) (3)
    M. Liu (1) (3)
    X. -X. Zhang (1) (3)
    L. Wang (1) (3)
    S. Zhang (1) (3)
    G. -B. Che (2) (3)
    Z. -L. Xu (3)
  • 关键词:organic ultraviolet photodetector ; Cu(I) complex ; photoluminescence quenching ; high response
  • 刊名:Opto-Electronics Review
  • 出版年:2013
  • 出版时间:September 2013
  • 年:2013
  • 卷:21
  • 期:3
  • 页码:288-292
  • 全文大小:362KB
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  • 作者单位:C. -B. Liu (1) (3)
    B. Su (2) (3)
    M. Liu (1) (3)
    X. -X. Zhang (1) (3)
    L. Wang (1) (3)
    S. Zhang (1) (3)
    G. -B. Che (2) (3)
    Z. -L. Xu (3)

    1. College of Chemistry, Jilin Normal University, Siping, Jilin1, 36000, People’s Republic of China
    3. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping, Jilin, 136000, People’s Republic of China
    2. College of Environmental Science and Engineering, Jilin Normal University, Siping, Jilin, 136000, People’s Republic of China
  • ISSN:1896-3757
文摘
We demonstrate high response organic ultraviolet photodetectors using 4,4-4-tris[3-methyl-pheny(phenyl)amino]tri-phenylamine (m-MTDATA) and two novel Cu(I) complexes, [Cu(DPEphos)(PyPhen)]BF4 (CuDP)(DPEphos = Bis [2-(diphenylphosphino)phenyl]ether, PyPhen = pyrazino[2,3-f][1,10]phenanthroline) and [Cu(DPEbenz)(PyPhen)]BF4 (CuBP) (DPEbenz = 1,2-bis(diphenylphosphino)benzene) to act as the electron donor and acceptor, respectively. Strong photoluminescence quenching of m-MTDATA by Cu(I) complexes is observed manifesting the efficient photoinduced charge transfer that occurs between m-MTDATA and Cu(I) complexes. The optimized photodetector based on CuBP exhibits a maximum response of 276 mA/W at ?2 V under an illumination of 365 nm UV light irradiation with an intensity of 1.75 mW/cm2. The high response is attributed to feasible energy level match, efficient electron transfer from m-MTDATA to CuBP and skillful device design. More detailed working mechanism of harvesting high performance is also discussed.

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