Thermal stability of soil organic matter was affected by 23-yr maize and soybean continuous cultivation in northeast of China
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  • 作者:Shu-jie Miao ; Yun-fa Qiao ; Meng-yang You…
  • 关键词:TG ; DSC ; Energy density ; SOM ; Continuous cropping
  • 刊名:Journal of Thermal Analysis and Calorimetry
  • 出版年:2016
  • 出版时间:March 2016
  • 年:2016
  • 卷:123
  • 期:3
  • 页码:2045-2051
  • 全文大小:794 KB
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  • 作者单位:Shu-jie Miao (1)
    Yun-fa Qiao (1)
    Meng-yang You (2)
    Fu-tao Zhang (2)

    1. Nanjing University of Information Sciences and Technology, Nanjing, 210044, Jiangsu Province, People’s Republic of China
    2. Northeast Institute of Geography and Agroecology, Chinese Academy of Sciences, Harbin, 150081, Heilongjiang Province, People’s Republic of China
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Sciences
    Polymer Sciences
    Physical Chemistry
    Inorganic Chemistry
    Measurement Science and Instrumentation
  • 出版者:Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
  • ISSN:1572-8943
文摘
Long-term continuous cropping affects the biochemical quality of soil organic matter (SOM), but whether the effects are relevant with their thermal stability is less clear. In northeast China, long-term continuous cropping occurred frequently owing to higher yield and economic interest requirement. To verify the thermal stability properties of SOM affected by the long-term continuous cropping, the study focused on 23-yr continuous cultivated maize and soybean plots, where the effect of cropping is likely to be detected. Bulk soils sampled in 1991 and 2014 were studied by thermogravimetry and differential scanning calorimetry (DSC). The results showed typical bimodal peaks in DSC curve in bulk Mollisols. A labile fraction peak was observed at 354–366 °C low-temperature zone and recalcitrant fraction one at high temperature of 430–438 °C. Energy density (J mg−1 OM) was greater in soybean plots compared to maize plots; in contrast, long-term continuous maize cultivation also increased energy density, in reverse in soybean plots after 23-yr cultivation. The DSC-T50, temperature at which half of energy release occurred, typically showed larger responses to long-term cultivation than crop species. Results obtained support the hypothesis of a potential link between long-term continuous cropping and the thermal stability of SOM, and a correlation with crop species.

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