Thermal and electrical properties of composites based on (3-mercaptopropyl) trimethoxysilane- and Cu-coated carbon fiber and silicone rubber

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• 作者：Xiong-wei Zhao ; Chong-guang Zang ; Qing-kun Ma ; Yu-quan Wen…
• 刊名：Journal of Materials Science
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：51
• 期：8
• 页码：4088-4095
• 全文大小：1,901 KB
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• 作者单位：Xiong-wei Zhao (1)
  Chong-guang Zang (1)
  Qing-kun Ma (2)
  Yu-quan Wen (1)
  Qing-jie Jiao (1)
  
  1. State Key Laboratory of Explosive Science and Technology, Beijing Institute of Technology, Beijing, 100081, People’s Republic of China
  2. Research Center of Yuxi Industries Group, Norinco Group, Nanyang, 473000, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Characterization and Evaluation Materials
  Polymer Sciences
  Continuum Mechanics and Mechanics of Materials
  Crystallography
  Mechanics
  
• 出版者：Springer Netherlands
• ISSN：1573-4803

文摘

In this paper, (3-mercaptopropyl)trimethoxysilane (MPTS)- and copper-coated carbon fiber (M–Cu-CF) was obtained by electroless plating method. The M–Cu-CF was evaluated by FTIR, XRD, TGA, and SEM. It was found that the MPTS and Cu were coated on the fiber surface successfully. The M–Cu-CF was utilized as a conductive filler in silicone rubber (SR) for thermal and electrical conductivity applications and exhibited good dispersion and compatibility with the matrix. The effect of M–Cu-CF content on the thermal conductivity and volume resistivity of silicone rubber composites was investigated. The results showed that the thermal conductivity of the M–Cu-CF/SR composites reached 1.99 W (m K)−1 with only 4.0 wt% filler loading, approximately 2.10 times higher than that of raw-CF/SR composites at the same loading. And with the increase of M–Cu-CF loading, the least volume resistivity of M–Cu-CF/SR composites was 3.5 × 103 Ω cm.