Investigation into experimental conditions and factors for cyclohexane oxidation with VO(acac)2

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• 作者：Xitong Ma (1)
  Na Xing (1)
  Qiong Wu (1)
  Liting Xu (1)
  Yongheng Xing (1)
  
• 关键词：VO(acac)2 ; Cyclohexane oxidation ; Mechanism ; Phthalic acid ; Additive
• 刊名：Chemical Research in Chinese Universities
• 出版年：2014
• 出版时间：December 2014
• 年：2014
• 卷：30
• 期：6
• 页码：991-996
• 全文大小：524 KB
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• 作者单位：Xitong Ma (1)
  Na Xing (1)
  Qiong Wu (1)
  Liting Xu (1)
  Yongheng Xing (1)
  
  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, P. R. China
  
• ISSN：2210-3171

文摘

The catalytic activity of VO(acac)2 for the cyclohexane(Cy) oxidation was studied. The effects of various parameters, such as the amounts of H2O2, HNO3, H2O and Cy were investigated. The highest total turnover number(TON) is 234, which can be increased to 353, 342 and 403, respectively with the adding of o-phthalic, m-phthalic or p-phthalic acid. A reaction mechanism was also supposed primarily.