A two-step reduction method for synthesizing graphene nanocomposites with a low loading of well-dispersed platinum nanoparticles for use as counter electrodes in dye-sensitized solar cells
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- 作者：Li Wan ; Qiuping Zhang ; Shimin Wang ; Xianbao Wang…
- 刊名：Journal of Materials Science
- 出版年：2015
- 出版时间：June 2015
- 年：2015
- 卷：50
- 期：12
- 页码：4412-4421
- 全文大小：1,695 KB
- 参考文献：1.Lee K, Lin L, Chen C, Suryanarayanan V, Wu C (2014) Preparation of high transmittance platinum counter electrode at an ambient temperature for flexible dye-sensitized solar cells. Electrochim Acta 135:578-84. doi:10.-016/?j.?electacta.-014.-5.-04 View Article
2.Tang Z, Wu J, Zheng M, Huo J, Lan Z (2013) A microporous platinum counter electrode used in dye-sensitized solar cells. Nano Energy 2(5):622-27. doi:10.-016/?j.?nanoen.-013.-7.-14 View Article
3.Cho C, Wu H, Lin C (2013) Impacts of sputter-deposited platinum thickness on the performance of dye-sensitized solar cells. Electrochim Acta 107:488-93. doi:10.-016/?j.?electacta.-013.-6.-23 View Article
4.Wu J, Tang Z, Huang Y, Huang M, Yu H, Lin J (2014) A dye-sensitized solar cell based on platinum nanotube counter electrode with efficiency of 9.05?%. J Power Sources 257:84-9. doi:10.-016/?j.?jpowsour.-014.-1.-90 View Article
5.Lee H, Horn MW (2013) Sculptured platinum nanowire counter electrodes for dye-sensitized solar cells. Thin Solid Films 540:208-11. doi:10.-016/?j.?tsf.-013.-4.-79 View Article
6.Wang C, Chen J, Huang K, Chen H, Wang Y, Hsu C, Vittal R, Lin J, Ho K (2013) A platinum film with organized pores for the counter electrode in dye-sensitized solar cells. J Power Sources 239:496-99. doi:10.-016/?j.?jpowsour.-013.-3.-80 View Article
7.Wan J, Fang G, Yin H, Liu X, Liu D, Zhao M, Ke W, Tao H, Tang Z (2014) Pt–Ni alloy nanoparticles as superior counter electrodes for dye-sensitized solar cells: experimental and theoretical understanding. Adv Mater 26(48):8101-106. doi:10.-002/?adma.-01403951 View Article
8.Bajpai R, Roy S, Kumar P, Bajpai P, Kulshrestha N, Rafiee J, Koratkar N, Misra DS (2011) Graphene supported platinum nanoparticle counter-electrode for enhanced performance of dye-sensitized solar cells. ACS Appl Mater Interface 3(10):3884-889. doi:10.-021/?am200721x View Article
9.Gong F, Wang H, Wang Z (2011) Self-assembled monolayer of graphene/Pt as counter electrode for efficient dye-sensitized solar cell. Phys Chem Chem Phys 13(39):17676-7682. doi:10.-039/?C1CP22542A View Article
10.Yue G, Wu J, Xiao Y, Huang M, Lin J, Fan L, Lan Z (2013) Platinum/graphene hybrid film as a counter electrode for dye-sensitized solar cells. Electrochim Acta 92:64-0. doi:10.-016/?j.?electacta.-012.-1.-20 View Article
11.Zhai P, Chang Y, Huang Y, Wei T, Su H, Feng S (2014) Water-soluble microwave-exfoliated graphene nanosheet/platinum nanoparticle composite and its application in dye-sensitized solar cells. Electrochim Acta 132:186-92. doi:10.-016/?j.?electacta.-014.-3.-45 View Article
12.Cheng C, Lin C, Shan C, Tsai S, Lin K, Chang C, Chien FS-S (2013) Platinum-graphene counter electrodes for dye-sensitized solar cells. J Appl Phys 114(1):014503. doi:10.-063/-.-812498 View Article
13.Li P, Wu J, Lin J, Huang M, Huang Y, Li Q (2009) High-performance and low platinum loading Pt/carbon black counter electrode for dye-sensitized solar cells. Sol Energy 83(6):845-49. doi:10.-016/?j.?solener.-008.-1.-12 View Article
14.Tripathi B, Yadav P, Pandey K, Kanade P, Kumar M, Kumar M (2014) Investigating the role of graphene in the photovoltaic performance improvement of dye-sensitized solar cell. Mat Sci Eng B-Solid 190:111-18. doi:10.-016/?j.?mseb.-014.-9.-16 View Article
15.Lin C, Lee C, Ho S, Wei T, Chi Y, Huang KP, He J (2014) Nitrogen-doped graphene/platinum counter electrodes for dye-sensitized solar cells. ACS Photonics 1(2):1264-269. doi:10.-021/?ph500219r View Article
16.Dao V, Larina LL, Suh H, Hong K, Lee J, Choi H (2014) Optimum strategy for designing a graphene-based counter electrode for dye-sensitized solar cells. Carbon 77:980-92. doi:10.-016/?j.?carbon.-014.-6.-15 View Article
17.Hoshi H, Tanaka S, Miyoshi T (2014) Pt-graphene electrodes for dye-sensitized solar cells. Mat Sci Eng B-Solid 190:47-1. doi:10.-016/?j.?mseb.-014.-9.-03 View Article
18.Trung NB, Tam TV, Kim HR, Hur SH, Kim EJ, Choi WM (2014) Three-dimensional hollow balls of graphene–polyaniline hybrids for supercapacitor applications. Chem Eng J 255:89-6. doi:10.-016/?j.?cej.-014.-6.-28 View Article
19.Tan Y, Zhu K, Li D, Bai F, Wei Y, Zhang P (2014) N-doped graphene/Fe–Fe3C nano-composite synthesized by a Fe-based metal organic framework and its anode performance in lithium ion batteries. Chem Eng J 258:93-00. doi:10.-016/?j.?cej.-014.-7.-66 View Article
20.Seger B, Kamat PV (2009) Electrocatalytically active graphene-platinum nanocomposites. Role of 2-D carbon support in PEM fuel cells. J Phys Chem C 113(19):7990-995. doi:10.-021/?jp900360k View Article
21.López Guerra E, Shanmugharaj AM, Choi WS, Ryu SH (2013) Thermally reduced graphene oxide-supported nickel catalyst for hydrogen production by propane steam reforming. Appl Catal A 468:467-74. doi:10.-016/?j.?apcata.-013.-9.-25 View Article
22.Ghaleb ZA, Mariatti M, - 作者单位：Li Wan (1)
Qiuping Zhang (1)
Shimin Wang (1)
Xianbao Wang (1)
Zhiguang Guo (1)
Binghai Dong (1)
Li Zhao (1)
Zuxun Xu (1)
Jing Li (1)
Bi Wang (1)
Tianyue Luo (1)
Huayu Xiong (1)
1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Key Laboratory for the Green Preparation and Application of Functional Materials, Ministry of Education, Faculty of Materials Science and Engineering, Hubei University, Wuhan, 430062, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Materials Science
Characterization and Evaluation Materials
Polymer Sciences
Continuum Mechanics and Mechanics of Materials
Crystallography
Mechanics - 出版者：Springer Netherlands
- ISSN：1573-4803
文摘
Low Pt-loaded graphene nanocomposites were prepared using a two-step reduction process. Graphene dispersion was first prepared from graphene oxide using hydrazine hydrate as a reducing agent. Pt-reduced graphene oxide composites were then synthesized in the aqueous graphene dispersion at 90?°C without the need for another reductant. Pt/graphene composite films were then deposited on fluorine-doped tin oxide substrates using a simple drop-casting method at room temperature and subsequently used as counter electrodes (CEs) in dye-sensitized solar cells (DSSCs). Cyclic voltammetry and electrical impedance analysis show that the composite electrodes have high electrocatalytic activity toward iodide/triiodide reduction. The energy conversion efficiency of the Pt/graphene CE-based DSSC was found to be 1.9?% lower than that of cells with a Pt-based CE.