Effect of block copolymer coupling agents on properties of mica reinforced polymeric composites

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• 作者：Xiaodong Zhou ; Ruohua Xiong and Qunfang Lin
• 刊名：Journal of Materials Science
• 出版年：2006
• 出版时间：December, 2006
• 年：2006
• 卷：41
• 期：23
• 页码：7879-7885
• 全文大小：260 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Characterization and Evaluation Materials
  Polymer Sciences
  Continuum Mechanics and Mechanics of Materials
  Crystallography
  Mechanics
  
• 出版者：Springer Netherlands
• ISSN：1573-4803

文摘

In the systems of mica reinforced polymers based on polystyrene and polypropylene, block copolymers polystyrene-b–polyisoprene-b–polyvinyltriethoxysilane (PS-b–PI-b–PVTOSI) and polystyrene–polyvinyltriethoxysilane (PS-b-PVTOSI) were used as macromolecular coupling agents to treat mica. Compared to common coupling agents, e.g. A-174, A-151 and A-1100, such block copolymer coupling agents can much more effectively improve the interfacial adhesion of mica reinforced polystyrene and significantly increase the mechanical properties of the composites. In a certain range, an appropriate increase in the block lengths of polystyrene and polyvinyltriethoxysilane is desirable for the mechanical properties. The introduction of the middle flexible polyisoprene block and the increase in its length are of advantage to the impact strength of the composites. The good compatibility of the matrix polymer and the block copolymer coupling agent is in favor of the improvement in the interfacial adhesion.