Fundamentals of numerical analysis of linear tension of two-dimensional drops

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• 作者：E. S. Zaitseva ; A. B. Rabinovich…
• 刊名：Protection of Metals and Physical Chemistry of Surfaces
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：52
• 期：1
• 页码：1-10
• 全文大小：636 KB
• 参考文献：1.Thomson, W.T., Philos. Mag., 1971, vol. 42, p. 448.
  2.Volmer, M. and Weber, A., Z. Phys., 1926, vol. 119, p. 277.
  3.Volmer, M., Kinetik der Phasenbilding, Dresden: Steinkopff, 1939.
  4.Rusanov, A.I., Fazovye ravnovesiya i poverkhnostnye yavleniya (Phase Equilibriums and Surface Events), Leningrad: Khimiya, 1967.
  5.Frenkel’, Ya.I., Kineticheskaya teoriya zhidkostei (Kinetic Theory of Liquids), Moscow: Akad. Nauk SSSR, 1945.
  6.Ono, S. and Kondo, S., Molecular Theory of Surface Tension in Liquids, Berlin: Springer-Verlag, 1960.
  7.Rowlinson, J.S. and Widom, B., Molecular Theory of Capillarity, Oxford, UK: Clarendon, 1982.
  8.Hill, T.L., Statistical Mechanics. Principles and Selected Applications, New York: McGraw-Hill, 1956.
  9.Robertson, D. and Pound, G.M., Crit. Rev., 1974, vol. 4, p. 163.
  10.Tovbin, Yu.K., Theory of Physical Chemistry Processes at a Gas-Solid Surface Processes, Boca Raton, FL.: CRC Press, 1991.
  11.Tovbin, Yu.K., molekulyarnaya teoriya adsorbtsii v poristykh telakh (Molecular Theory of Adsorption in Porous Bodies), Moscow: Fizmatlit, 2012.
  12.Tovbin, Yu.K., Russ. J., 2010, vol. 84, no. 2, p. 180.
  13.Tovbin, Yu.K. and Rabinovich, A.B., Russ. Chem., 2009, vol. 58, no. 11, p. 2193.CrossRef
  14.Tovbin, Yu.K. and Rabinovich, A.B., Russ. Chem., 2010, vol. 59, no. 4, p. 677.CrossRef
  15.Tovbin, Yu.K. and Rabinovich, A.B., Russ. Chem., 2010, vol. 59, no. 4, p. 857.CrossRef
  16.Tovbin, Yu.K., Prot. Met., 2010, vol. 46, no. 3, p. 309.
  17.Tovbin, Y.K., Russ. J., 2010, vol. 84, no. 10, p. 1717.
  18.Tovbin, Yu.K. and Rabinovich, A.B., Russ. J., 2011, vol. 85, no. 8, p. 1398.
  19.Heer, C.V., Statistical Mechanics, Kinetic Theory and Stochastic Process, New York: Academic, 1972.
  20.Huang, K., Statistical Mechanics, New York: Wiley, 1963.
  
• 作者单位：E. S. Zaitseva (1)
  A. B. Rabinovich (1)
  Yu. K. Tovbin (1)
  
  1. Karpov Physicochemical Research Institute, per. Obukha 3-1/12, str. 6, Moscow, 105064, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Tribology, Corrosion and Coatings
  Materials Science
  Metallic Materials
  Inorganic Chemistry
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：2070-206X

文摘

Fundamentals of numerical analysis of linear tension of two-dimensional drops of molecules adsorbed on uniform crystal faces have been developed. A lattice-gas model has been applied for description of adsorption. Molecular distributions have been computed in a quasi-chemical approximation, allowing for the effects of direct correlations of interacting particles. Differences in the algorithms of calculation of linear tension on a two-dimensional vapor–liquid interface connected with the effect of the transition region structure, taking into account metastability of coexisting small phases, and a variation in methods of determining line tension at a curved interface according to the material balance condition (equimolecular line) or mechanical equilibrium condition. This has allowed us to compute the equilibrium molecular distribution in small two-dimensional drops and the linear tension value at the interface as a function of the drop size and temperature. Original Russian Text © E.S. Zaitseva, A.B. Rabinovich, Yu.K. Tovbin, 2016, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2016, Vol. 52, No. 1, pp. 3–12.