A comparative study using liquid scintillation counting to determine 63Ni in low and intermediate level radioactive waste
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- 作者：Céline Gautier ; Christèle Colin…
- 关键词：63Ni ; Radiochemical analysis ; Liquid scintillation counting ; Decommissioning ; Radioactive waste ; Dimethylglyoxime
- 刊名：Journal of Radioanalytical and Nuclear Chemistry
- 出版年：2016
- 出版时间：April 2016
- 年：2016
- 卷：308
- 期：1
- 页码：261-270
- 全文大小：755 KB
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Christèle Colin (1)
Cécile Garcia (1)
1. CEA Saclay, DEN/DANS/DPC/SEARS/LASE, F-91191, Gif-sur-Yvette Cedex, France - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Nuclear Chemistry
Physical Chemistry
Nuclear Physics, Heavy Ions and Hadrons
Diagnostic Radiology
Inorganic Chemistry - 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
- ISSN：1588-2780
文摘
A comparative study using liquid scintillation counting was performed to measure 63Ni in low and intermediate level radioactive waste. Three dimethylglyoxime (DMG)-based radiochemical procedures (solvent extraction, precipitation, extraction chromatography) were investigated, the solvent extraction method being considered as the reference method. Theoretical speciation calculations enabled to better understand the chemical reactions involved in the three protocols and to optimize them. In comparison to the method based on DMG precipitation, the method based on extraction chromatography allowed to achieve the best results in one single step in term of recovery yield and accuracy for various samples.