Surface peeling of cellulose nanocrystals resulting from periodate oxidation and reductive amination with water-soluble polymers

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• 作者：Firas Azzam ; Magali Galliot ; Jean-Luc Putaux ; Laurent Heux ; Bruno Jean
• 关键词：Cellulose nanocrystals ; Periodate oxidation ; Reductive amination ; Peeling
• 刊名：Cellulose
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：22
• 期：6
• 页码：3701-3714
• 全文大小：1,666 KB
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• 作者单位：Firas Azzam (1) (2)
  Magali Galliot (1) (2)
  Jean-Luc Putaux (1) (2)
  Laurent Heux (1) (2)
  Bruno Jean (1) (2)
  
  1. Univ. Grenoble Alpes, CERMAV, 38000, Grenoble, France
  2. CNRS, CERMAV, 38000, Grenoble, France
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Bioorganic Chemistry
  Physical Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer Netherlands
• ISSN：1572-882X

文摘

Cellulose nanocrystals (CNCs) were first submitted to periodate oxidation for increasing reaction times and subsequently to reductive amination with water-soluble amine-terminated polymers. The morphology and chemical properties of the samples were characterized by imaging (TEM), spectroscopic (FTIR and 13C solid-state NMR), and scattering techniques (DLS and WAXS). The data revealed that the periodate oxidation of CNCs resulted in an increase in the degree of oxidation (DO) with reaction time and that most of the created carbonyls were converted into hemiacetals as a result of their interaction with vicinal hydroxyl groups. Like in the case of cellulose microfibrils, CNCs were oxidized from the surface to the core of the particles. For low reaction times and concomitant low DOs, the morphology and crystallinity of the CNCs were mildly altered. A prolonged oxidation resulted in the separation of the originally laterally assembled crystallites and the data are consistent with the presence of dangling chains resulting from the cleavage of glucosyl units at the surface of the thin elongated cellulose nanoparticles. A comparison with literature data further showed that the oxidation reaction was not primarily governed by the degree of crystallinity. Remarkably, after reductive amination with water-soluble polymer chains, thin unoxidized crystalline cellulose nanoparticles were recovered. This situation seems to result from the surface peeling of the CNCs due to reaction of surface-oxidized dangling chains with water-soluble polymers and their subsequent solubilization. Keywords Cellulose nanocrystals Periodate oxidation Reductive amination Peeling