Hydrocarbon Oxidation with H2O2, Catalyzed by Iron Complexes with a Polydentate Pyridine-Based Ligand
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- 作者：Stefania Tanase (1) (2)
Jan Reedijk (2)
Ronald Hage (3)
Gadi Rothenberg (1) - 关键词：Iron ; Pentadentate ligand ; Catalytic oxidation
- 刊名：Topics in Catalysis
- 出版年：2010
- 出版时间：September 2010
- 年：2010
- 卷：53
- 期：15-18
- 页码：1039-1044
- 全文大小：254KB
- 参考文献：1. Que L, Tolman WB (2008) Nature 455:333 CrossRef
2. Tanase S, Bouwman E (2006) Adv Inorg Chem 58:29 CrossRef
3. Meunier B (2000) Biomimetic oxidations catalyzed by transition metal complexes. Imperial College Press, London CrossRef
4. Rothenberg G (2008) Catalysis: concepts and green applications. Wiley-VCH, Weinheim
5. Tolman WB (2006) Activation of small molecules: organometallic and bioinorganic perspectives. Wiley-VCH, Weinheim
6. Costas M, Mehn MP, Jensen MP, Que L (2004) Chem Rev 104:939 CrossRef
7. Solomon EI, Brunold TC, Davis MI, Kemsley JN, Lee SK, Lehnert N, Neese F, Skulan AJ, Yang YS, Zhou J (2000) Chem Rev 100:235 CrossRef
8. Tshuva EY, Lippard SJ (2004) Chem Rev 104:987 CrossRef
9. Balland V, Banse F, Anxolabehere-Mallart E, Ghiladi M, Mattioli TA, Philouze C, Blondin G, Girerd JJ (2003) Inorg Chem 42:2470 CrossRef
10. Balland V, Banse F, Anxolabehere-Mallart E, Nierlich M, Girerd JJ (2003) Eur J Inorg Chem 13:2529 CrossRef
11. Balland V, Mathieu D, Pons-Y-Moll N, Bartoli JF, Banse F, Battioni P, Girerd JJ, Mansuy D (2004) J Mol Catal A 215:81 CrossRef
12. Goldsmith CR, Jonas RT, Stack TDP (2002) J Am Chem Soc 124:83 CrossRef
13. Jensen KB, McKenzie CJ, Nielsen LP, Pedersen JZ, Svendsen HM (1999) Chem Commun 1313
14. Roelfes G, Lubben M, Chen K, Ho RYN, Meetsma A, Genseberger S, Hermant RM, Hage R, Mandal SK, Young VG, Zang Y, Kooijman H, Spek AL, Que L, Feringa BL (1999) Inorg Chem 38:1929 CrossRef
15. Roelfes G, Lubben M, Hage R, Que L, Feringa BL (2000) Chem Eur J 6:2152 CrossRef
16. Taktak S, Ye WH, Herrera AM, Rybak-Akimova EV (2007) Inorg Chem 46:2929 CrossRef
17. Tang JK, Gamez P, Reedijk J (2007) Dalton Trans 4644
18. Nakamoto K (1963) Infrared spectra of inorganic and coordination compounds. Wiley, New York
19. Hauser A, Vef A, Adler P (1991) J Chem Phys 95:8710 CrossRef
20. Solomon eI, Brunold TC, Kemsley JN, Lee SK, Lehnert N, Neese F, Skulan AJ, Yang Ys (2000) J Zhou Chem Rev 100:235 CrossRef
21. Norman RE, Holz RC, Menage S, Oconnor CJ, Zhang JH, Que L (1990) Inorg Chem 29:4629 CrossRef
22. Gorun SM, Lippard SJ (1991) Inorg Chem 30:1625 CrossRef
23. Tanase S, Foltz C, de Gelder R, Hage R, Bouwman E, Reedijk J (2005) J Mol Catal A 225:161 CrossRef
24. Tanase S, Marques-Gallego P, Browne WR, Hage R, Bouwman E, Feringa BL, Reedijk J (2008) Dalton Trans 2026
25. Appleton AJ, Evans S, Smith JRL (1996) J Chem Soc Perkin Trans 3:281
26. Kaizer J, Klinker EJ, Oh NY, Rohde JU, Song WJ, Stubna A, Kim J, Munck E, Nam W, Que L (2004) J Am Chem Soc 126:472 CrossRef - 作者单位：Stefania Tanase (1) (2)
Jan Reedijk (2)
Ronald Hage (3)
Gadi Rothenberg (1)
1. Van’t Hoff Insitute of Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands
2. Gorlaeus Laboratories, Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA, Leiden, The Netherlands
3. Rahu Catalytics, BioPartner Center Leiden, Wassenaarseweg 72, 2333 AL, Leiden, The Netherlands - ISSN：1572-9028
文摘
We report the structural and functional features of two new catalysts: a mononuclear [Fe(N5mpy)(CH3CN)](BF4)2 (N5mpy?=?(N,N′E,N,N′E)-N,N-(pyridine-2,6-diylbis(ethan-1-yl-1-ylidene))bis(1-(pyridin-2-yl)methanamine)) complex and a binuclear {[Fe(N5mpy)]2O}(BF4)4 complex. Both compounds catalyze the oxidation of alkanes by H2O2, in MeCN or acetone to yield alcohols and ketones. Moderate to good yields are obtained with various cyclic and benzylic alkanes. Screening of several substrates revealed that higher yields are obtained for the oxidation of alkanes with low C–H bond dissociation energies. The ratio alcohol/ketone observed suggests the involvement of iron-based oxidizing species.