Syntheses of flame-retardant cellulose esters and their fibers

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• 作者：Yunbo Zheng ; Jun Song ; Bowen Cheng ; Xiaolin Fang
• 关键词：Cellulose ; Homogeneous modification ; Ionic liquid ; Fire ; retardant fiber
• 刊名：Fibers and Polymers
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：17
• 期：1
• 页码：1-8
• 全文大小：899 KB
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• 作者单位：Yunbo Zheng (1)
  Jun Song (1)
  Bowen Cheng (2)
  Xiaolin Fang (1)
  
  1. School of Material Science and Engineering, Tianjin Polytechnic University, Tianjin, 300387, P.R. China
  2. School of Textile, Tianjin Polytechnic University, Tianjin, 300387, P.R. China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：The Korean Fiber Society
• ISSN：1875-0052

文摘

3-(Hydroxyphenylphosphinyl)-propanoic acid (3-HPP) esters of cellulose (HPP-Cellulose) were synthesized homogeneously in ionic liquid 1-butyl-3-methylimidazoliumchloride by in situ activation. The chemical structure of the cellulose esters is characterized by FTIR and NMR. The degree of substitution was easily controlled within 0.38-1.51 by varying the molar ratio of 3-HPP/anhydroglucose unit, reaction time, and temperature. All the products showed excellent solubility in common organic solvents. The results of TGA, DTG, LOI, and cone calorimeter test show that 3-HPP has a positive influence on the thermal properties and flame retardance of cellulose. Based on the volatilized products analysis by TGA-IR, the presence of 3-HPP reduces the intensity of volatilized product and accelerates the dehydration action. Moreover, the addition of cellulose (3 wt%) is beneficial to prepare HPP-Cellulose fibers using a dry-wet spinning technique, and the blended fibers possess good mechanical properties as well as flame resistance. Keywords Cellulose Homogeneous modification Ionic liquid Fire-retardant fiber