Mobilization of aluminum by the acid percolates within unsaturated zone of sandstones

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• 作者：Tomá? Navrátil (1)
  Zuzana Va?ilová (2)
  Jan Rohovec (1)
  
• 关键词：Acidification ; Drip water ; Chemical weathering ; Salt efflorescence ; Black Triangle ; Bohemian Switzerland National Park ; Czech Republic
• 刊名：Environmental Monitoring and Assessment
• 出版年：2013
• 出版时间：September 2013
• 年：2013
• 卷：185
• 期：9
• 页码：7115-7131
• 全文大小：539KB
• 参考文献：1. Adamovi?, J., Mikulá?, R., Schweigstillová, J., & Bohmová, V. (2011). Porosity changes induced by salt weathering of sandstones, Bohemian Cretaceous Basin, Czech Republic. / Acta Geodynamica et Geomaterialia, 8, 29-5.
  2. Bruthans J., & Schweigstillová, J. (2009). Al-enriched water from unsaturated zone of sandstone: The most acidified environment in the Czech Republic by the atmospheric deposition? (In Czech), p.53. Extended Abstract Book of the Czech International Hydrogeological Congress, Ostrava.
  3. ?ech, S., Klein, V., K?í?, J., & Vale?ka, J. (1980). Revision of the Upper Cretaceous stratigraphy of the Bohemian Cretaceous Basin. / Bulletin of the Czech Geological Survey, 55(5), 277-96.
  4. ?erny, J. (1995). Recovery of acidified catchments in the extremely polluted Krusne Hory Mts., Czech Republic. Abstract Book of the ACID REIGN 95? Conference, p. 295.
  5. CHMI, (2009). database of Czech Hydrometeorological Institute, data on station ústí nad Labem-Ko?kov. http://old.chmi.cz/meteo/opss/stanice.php?ukazatel=ustinlab Accessed July 2012.
  6. CHMI, (2012). Assessmnet and reference reports of water monitoring. Database of Czech Hydrometeorological Institute wells VP8503 and VP8431. http://hydro.chmi.cz/isarrow/Accessed July 2012.
  7. Drever, J. I., & Stillings, L. L. (1997). The role of organic acids in mineral weathering. / Colloids and Surfaces A: Physicochemical and Engineering Aspects, 120, 167-81. CrossRef
  8. Edmunds, W. M., Kinniburgh, D. G. & Moss, P. D. (1992). Trace metals in interstitial waters from sandstones -acidic inputs to shallow groundwaters. / Environmental Pollution, 77(2-), 129-41.
  9. EMEP, (2012). Database of the EMEP Centre on Emission Inventories and Projections (CEIP) www.ceip.at Accessed July 2012.
  10. Fest, E. P. M. J., Temminghoff, E. J. M., Griffioen, J., Van Der Grift, B., & Van Riemsdijk, V. H. (2007). Groundwater chemistry of Al under Dutch sandy soils: effects of land use and depth. / Applied Geochemistry, 22(7), 1427-438. CrossRef
  11. Guan, H., Love, A. J., Simmons, C. T., Ding, Z. Y., & Hutson, J. L. (2010). Catchment conceptualisation for examining applicability of chloride mass balance method in an area of historical forest clearance. / Hydrology and Earth System Sciences, 14, 1233-245. CrossRef
  12. H?rtel, H., Sádlo, J., Swierkosz, K., & Marková, I. (2007). Phytogeography of sandstone areas in Bohemian Cretaceous Basin (Czech Republic/Germany/Poland). In H. H?rtel, V. Cílek, T. Herben, A. Jackson, & R. Williams (Eds.), / Sandstone Landscapes (pp. 177-89). Prague: Administration of the Bohemian Switzerland National Park and Academia.
  13. H?rtel, H., ?teflová, D., & Drozd, J. (2008). Management plan on the Bohemian Switzerland National Park, 2009-016 (In Czech). Krásná Lípa, 217?pp.
  14. Her?ík, F., Hermann, Z., & Vale?ka, J. (1999). / Hydrogeology of the Bohemian Cretaceous Basin (In Czech). Prague: Czech Geological Survey.
  15. Hru?ka, J., & Cienciala, E. (2003). / Long-term acidification and nutrient degradation of forest soils - limiting factors of forestry today. Prague: Ministry of Environment.
  16. Hru?ka, J., & Majer, V. (1996). Retention of human induced sulphur in soils: a factor preventing acidification in surface water of Bohemian Forest (In Czech). / Silva Gabreta, 1, 143-49.
  17. Jiráková, H., Huneau, F., Hrkal, Z., Celle-Jeanton, H., & Le Coustumer, P. (2010). Carbon isotopes to constrain the origin and circulation pattern of groundwater in the north-western part of the Bohemian Cretaceous Basin (Czech Republic). / Applied Geochemistry, 25, 1265-279. CrossRef
  18. Kjoller, C., Postma, D., & Larsen, F. (2004). Groundwater acidification and the mobilization of trace metals in sandy aquifer. / Environmental Science & Technology, 38, 2829-835. CrossRef
  19. Kohout, P. (2010a). Geochemical monitoring of groundwater (In Czech). Final report 2010. ALS Czech Republic, Prague. http://www.npcs.cz/geochemie-geologie-hydrologie-hydrogeologie Accessed August 2012.
  20. Kohout, P. (2010b). Geochemical monitoring of surface waters (In Czech). Final report 2010. ALS Czech Republic, Prague. http://www.npcs.cz/geochemie-geologie-hydrologie-hydrogeologie Accessed August 2012.
  21. Kopá?ek, J., & Vesely, J. (2005). Sulfur and nitrogen emissions in the Czech Republic and Slovakia from 1850 till 2000. / Atmospheric Environment, 39, 2179-188. CrossRef
  22. Lo?ek, V. (2007). Zrcadlo Minulosti—mirror of the past. (In Czech) Doko?án, Prague.
  23. Meesenburg, H., Meiwes, K. J., & Rademacher, P. (1995). Long term trends in atmospheric deposition and seepage output in northwest German forest ecosystems. / Water, Air, and Soil Pollution, 85, 611-16. CrossRef
  24. Melounová, L. (2006). Salt weathering of Upper Cretaceous sandstones of the Wing Wall cliffs (National Park Bohemian Switzerland) (In Czech). Unpublished MSc.thesis, Institute of Geochemistry, Mineralogy and Mineral Resources, Charles University Prague, 48?pp.
  25. Navrátil, T., Rohovec, J., Amirbahman, A., Norton, S., & Fernandez, I. (2009). Amorphous aluminum hydroxide control on sulfate and phosphate in sediment-solution systems. / Water, Air, and Soil Pollution, 201(1-), 87-8. CrossRef
  26. Navrátil, T., Norton, S., Fernandez, I., & Nelson, S. (2010). Twenty-year inter-annual trends and seasonal variations in precipitation and stream water chemistry at the Bear Brook Watershed in Maine, USA. / Environmental Monitoring and Assessment, 171, 23-5. CrossRef
  27. Oulehle, F., Hofmeister, J., & Hru?ka, J. (2007). Modeling of the long-term effect of tree species (Norway spruce and European beech) on soil acidification in the Ore Mountains. / Ecological Modelling, 204, 359-71. CrossRef
  28. Patzelt, Z. (2007). Groundwater chemistry of the Bohemian Switzerland National Park (Czech Republic). In H. H?rtel, V. Cílek, T. Herben, A. Jackson, & R. Williams (Eds.), / Sandstone landscapes (pp. 93-6). Prague: Administration of the Bohemian Switzerland National Park and Academia.
  29. P?ikryl, R. (2004). Comparison of mineralogical composition of crusts formed on natural stone in the natural environment and on monuments. In A. S. Goudie & J. Kalvoda (Eds.), / Geomorphological variations (pp. 143-56). P3K, Prague.
  30. P?ikryl, R., Melounová, L., Va?ilová, Z., & Weishauptová, Z. (2007). Spatial relationships of salt distribution and related physical changes of underlying rocks on naturally weathered sandstone exposures (Bohemian Switzerland National Park, Czech Republic). / Environmental Geology, 52, 409-20. CrossRef
  31. Sádlo, J., H?rtel, H., & Marková, I. (2007). Diversity of flora and vegetation of the sandstone areas in the Bohemian Cretaceous Basin (Czech Republic). In H. H?rtel, V. Cílek, T. Herben, A. Jackson, & R. Williams (Eds.), / Sandstone landscapes (pp. 161-76). Prague: Academia.
  32. Schecher, W. D., & McAvoy, D. C. (1992). A Software Environment for Chemical Equlibrium Modeling. / Computer Environment and Urban Systems, 16, 65-6. CrossRef
  33. Schweigstillová, J., P?ikryl, R., & Novotná, M. (2009). Isotopic composition of salt efflorescence from the sandstone castellated rocks of the Bohemian Cretaceous Basin (Czech Republic). / Environmental Geology, 58, 217-25. CrossRef
  34. Soukupová, J., Hradil, D., & P?ikryl, R. (2002). Chemical weathering of sandstone matrix—controls and case studies. In R. P?ikryl & H. A. Viles (Eds.), / Understanding and managing stone decay (pp. 263-71). Charles University Prague: Karolinum Press.
  35. Uli?ny, D., Hladiková, J., & Hradecká, L. (1993). Record of sea-level changes, oxygen depletion and the d13C anomaly across the Cenomanian–Turonian boundary, Bohemian Cretaceous Basin. / Cretaceous Research, 14, 211-34. CrossRef
  36. Uli?ny, D., Laurin, J., & ?ech, P. (2009). Controls on clastic sequence geometries in a shallow-marine, transtensional basin: the Bohemian Cretaceous Basin, Czech Republic. - / Sedimentology, 56, 1077-114.
  37. Vale?ka, J. (1997). / Bohemian Switzerland, geological and natural map 1:25 000. Prague: Czech Geological Survey.
  38. Va?ilová, Z. (2002). A review of selected sandstone weathering forms in Bohemian Switzerland National Park, Czech Republic. In R. P?ikryl & H. A. Viles (Eds.), / Understanding and managing stone decay. Charles University Prague: Karolinum Press.
  39. Va?ilová, Z., & Belisová, N. (Eds.). (2010). / Prav?ická brána rock Arch—the big book about the big arch (In Czech/German) (p. 193). Prague: Academia.
  40. Va?ilová, Z., Navrátil, T., & Dobe?ová, I. (2011a). Recent atmospheric deposition and its effects on sandstone cliffs in Bohemian Switzerland National Park, Czech Republic. / Water, Air, and Soil Pollution, 220, 117-30. CrossRef
  41. Va?ilová, Z., P?ikryl, R., & Cílek, V. (2011b). Prav?ice Rock Arch (Bohemian Switzerland National Park, Czech Republic) deterioration due to natural and anthropogenic weathering. / Environmental Earth Science, 63, 1861-878. CrossRef
  42. Wang, X., Li, Q., Hu, H., Zhang, T., & Zhou, Y. J. (2005). Dissolution of kaolinite induced by citric, oxalic, and malic acids. / Journal of Colloid Interface Scence, 290, 481-88. CrossRef
  43. Weed, R., & Norton, S. A. (1991). Siliceous crusts, quartz rinds, and biotic weathering of sandstones in the cold desert of Antarctica. In J. Berteline (Ed.), / Diversity of environmental geochemistry (pp. 225-48). Amsterdam: Elsevier.
  
• 作者单位：Tomá? Navrátil (1)
  Zuzana Va?ilová (2)
  Jan Rohovec (1)
  
  1. Institute of Geology AS CR, v.v.i., Rozvojová 269, Prague 6, 165 00, Czech Republic
  2. The Museum of the Town of ústí nad Labem, Masarykova 1000/3, 400 01, ústí nad Labem, Czech Republic
  

文摘

The area of the Black Triangle has been exposed to extreme levels of acid deposition in the twentieth century. The chemical weathering of sandstones found within the Black Triangle became well-known phenomenon. Infiltration of acid rain solutions into the sandstone represents the main input of salt components into the sandstone. The infiltrated solutions–sandstone percolates–react with sandstone matrix and previously deposited materials such as salt efflorescence. Acidic sandstone percolates pH-.2-.8 found at ten sites within the National Park Bohemian Switzerland contained high Al-tot (0.8-0?mg?L?) concentrations and high concentrations of anions SO4 (5-6?mg?L?) and NO3 (2-2?mg?L?). A high proportion (50-8?%) of Al-tot concentration in acid percolates was represented by toxic reactive Aln+. Chemical equilibrium modeling indicated as the most abundant Al species Al3+, AlSO4 +, and AlF2+. The remaining 2-0?% of Al-tot concentration was present in the form of complexes with dissolved organic matter Al-org. Mobilization and transport of Al from the upper zones of sandstone causes chemical weathering and sandstone structure deterioration. The most acidic percolates contained the highest concentrations of dissolved organic material (estimated up to 42?mg?L?) suggesting the contribution of vegetation on sandstone weathering processes. Very low concentrations of Al-tot in springs at BSNP suggest that Al mobilized in unsaturated zone is transported deeper into the sandstone. This process of mobilization could represent a threat for the water quality small-perched aquifers.