Latent ruthenium carbene complexes with six-membered N- and S-chelate rings

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• 作者：N. M. Shcheglova ; V. D. Kolesnik ; R. V. Ashirov…
• 关键词：Key wordsmetathesis ; carbene complexes ; ruthenium ; catalyst ; polymerization ; dicyclopentadiene ; polydicyclopentadiene
• 刊名：Russian Chemical Bulletin
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：65
• 期：2
• 页码：490-497
• 全文大小：295 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Organic Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-9171
• 卷排序：65

文摘

New ruthenium carbene complexes with chelating N- and S-benzylidene ligands were synthesized by the reactions of second- and third-generation Grubbs catalysts with ortho-vinylbenzyl-substituted amines or sulfides. These complexes were shown to exhibit catalytic activity in ring-opening metathesis polymerization and ring-closing metathesis.