Poly (3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) Zr(IV) phosphate composite cation exchanger : sol-gel synthesis and physicochemical characterization

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• 作者：Ali Mohammad (1)
  Inamuddin (1)
  Sardar Hussain (1)
  
  1. Department of Applied Chemistry ; Faculty of Engineering and Technology ; Aligarh Muslim University ; Aligarh ; 202002 ; India
  
• 关键词：PEDOT ; PSS Zr(IV) phosphate ; Sol ; gel synthesis ; Physicochemical characterization ; Ion exchange properties
• 刊名：Ionics
• 出版年：2015
• 出版时间：April 2015
• 年：2015
• 卷：21
• 期：4
• 页码：1063-1071
• 全文大小：1,423 KB
• 参考文献：1. Mockaitis, G, Rodrigues, JA, Foresti, E, Zaiat, M (2012) Toxic effects of cadmium (Cd2+) on anaerobic biomass: kinetic and metabolic implications. J Environ Manage 106: pp. 75-84 CrossRef
  2. Boparai, HK, Joseph, M, Carroll, DMO (2011) Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. J Hazard Mater 15: pp. 458-465 CrossRef
  3. Maleki, AA, Mahvi, H, Zazouli, MA, Izanloo, H, Barati, AH (2011) Aqueous cadmium removal by adsorption on barley hull and barley hull ash. Asian J Chem 23: pp. 1373-1376
  4. Wu, J, Lu, J, Chen, T, He, Z, Su, Y, Yao, XY (2010) In situ bio treatment of acidic mine drainage using straw as sole substrate. Environ Earth Sci 60: pp. 421-429 CrossRef
  5. Yavuz, O, Guzel, R, Aydin, F, Tegin, I, Ziyadanogullari, R (2007) Removal of cadmium and lead from aqueous solution by calcite. Polish J Environ Stud 16: pp. 467-471
  6. Henson, MC, Chedrese, PJ (2004) Endocrine disruption by cadmium, a common environmental toxicant with paradoxical effects on reproduction. Exp Biol Med 229: pp. 383-392
  7. Cadmium in drinking water (2003) Background document for preparation of WHO guidelines for drinking water quality, Geneva, World Health Organization, WHO, (WHO/SDE/WSH/03.04/80)
  8. Jarup, L, Akesson, A (2009) Current status of cadmium as an environmental health problem. Toxicol App Pharm 238: pp. 201-208 CrossRef
  9. Visa, M, Du牛a, A (2008) Cadmium and Nickel removal from waste water using modified fly ash: thermodynamic and kinetic Study. Sci Stud Res 9: pp. 73-82
  10. Ozar, A, Pirincci, HB (2006) The adsorption of Cd (II) ions on sulfuric acid-treated wheat bran. J Hazard Mater 137: pp. 849-855 CrossRef
  11. Mousavi, HZ, Seyedi, SR (2011) Nettle ash as a low cost adsorbent for the removal of nickel and cadmium from wastewater. Int J Environ Sci Technol 8: pp. 195-202 CrossRef
  12. Alam, Z, Inamuddin, NSA (2010) Synthesis and characterization of a thermally stable strongly acidic Cd(II) ion selective composite cation exchanger: polyaniline Ce(IV) molybdate. Desalination 250: pp. 515-522 CrossRef
  13. AL-Othman, ZA, Naushad, M, Inamuddin, (2011) Organic鈥搃norganic type composite cation exchanger poly-o-toluidine Zr(IV) tungstate, preparation, physicochemical characterization and its analytical application in separation of heavy metals. J Chem Engg 172: pp. 369-375 CrossRef
  14. Kaewsarn, P, Yu, Q (2001) Cadmium(II) removal from aqueous solutions by pre-treated biomass of marine alga Padina sp. Environ Pollut 112: pp. 209-213 CrossRef
  15. Blocher, C, Dorda, J, Marrov, V, Chemiel, H, Lazaridis, NK, Matis, KA (2003) Hybrid flotation- membrane filtration process for the removal of heavy metal ions from wastewater. Water Res 37: pp. 4108-4026 CrossRef
  16. Mahvi, AH, Bazrafshan, E (2007) Removal of cadmium from industrial effluents by electrocoagulation process using aluminum electrodes. World Appl Sci J 2: pp. 34-39
  17. Esalah, OJ, Weber, ME, Vera, JH (2000) Removal of lead, cadmium and zinc from aqueous solutions by precipitation with sodium di-(n-octyl) phosphinate. Can J Chem Eng 78: pp. 948-954 CrossRef
  18. Chen, GH (2004) Electrochemical technologies in wastewater. Sep Purif Technol 38: pp. 11-41 CrossRef
  19. Khan, A, Asiri, AM (2012) Review on composite cation exchange as interdisciplinary materials in analytical chemistry. Int J Electrochem Sci 7: pp. 3854-3902
  20. Khan, AA, Akhtar, T (2008) Preparation, physico-chemical characterization and electrical conductivity measurement studies of an organic鈥搃norganic nanocomposite cation-exchanger: poly-o-toluidine Zr(IV) phosphate. Electrochim Acta 53: pp. 5540-5548 CrossRef
  21. Khan, AA, Inamuddin, , Alam, MM (2005) Preparation, characterization and analytical applications of a new and novel electrically conducting fibrous type polymeric鈥搃norganic composite material: polypyrrole Th(IV) phosphate used as a cation exchanger and Pb(II) ion-selective membrane electrode. Mater Res Bull 40: pp. 289-305 CrossRef
  22. Khan, AA, Khan, A, Inamuddin, (2007) Preparation and characterization of a new organic鈥搃norganic nano-composite poly-o-toluidine Th(IV) phosphate: its analytical applications as cation-exchanger and in making ion-selective electrode. Talanta 72: pp. 699-710 CrossRef
  23. Rahman FU, Khan SN (2012) Therapeutic applications of ion exchange resins. In: Inamuddin, Luqman M (eds) Ion exchange technology II. Applications, Springer, U.K, pp 149鈥?68
  24. Naushad M, AL-Othman ZA (2012) Ion exchange materials and environmental remediation. In: Inamuddin, Luqman M (eds) Ion exchange technology II. Applications, Springer, U.K., pp 217鈥?35
  25. Mangold, KM, Weidlich, C, Schuster, K, Juttner, K (2005) Ion exchange properties and selectivity of PSS in an electrochemically switchable PPy matrix. J Appl Electrochem 35: pp. 1293-1301 CrossRef
  26. Osterholmes, AM, Shen, DE, Dyer, AL, Reynolds, JR (2013) Optimization of PEDOT films in ionic liquid supercapacitors: demonstration as a power source for polymer electrochromic devices. Appl Mater Interfaces 5: pp. 13432-13440 CrossRef
  27. Reiliy, CN, Schmidt, RW, Sadek, FS (1959) Chelon approach to analysis: I. survey of theory and applications. J Chem Educ 36: pp. 555-565 CrossRef
  28. Hebeish, A, Higazy, A, El-Shafei, A, Sharaf, S (2010) Synthesis of carboxymethyl cellulose (CMC) and starch-based hybrids and their applications in flocculation and sizing. Carbohydr Polym 79: pp. 60-69 CrossRef
  29. Rao, CNR (1963) Chemical applications of infrared spectroscopy. Academic, New York
  30. Liang, S, Teng, F, Bulgan, G, Zong, R, Zhu, Y (2008) Effect of phase structure of MnO2 nanorod catalyst on the activity for CO oxidation. J Physical Chem C 112: pp. 5307-5315 CrossRef
  31. Nilchi, A, Maalek, B, Kanchi, A, Maragheh, MG, Bagheri, A (2006) Cerium (IV) molybdate cation exchanger, synthesis, properties and ion separation capabilities. Radiat Phys Chem 75: pp. 301-308 CrossRef
  32. Ibrahim, AA, Adel, AM, El-Wahab, ZHA, Al-Shemy, MT (2011) Utilization of carboxymethyl cellulose based on bean hulls as chelating agent-synthesis, characterization and biological activity. Carbohydr Polym 83: pp. 94-115 CrossRef
  33. Lagashetty, A, Havanoor, V, Basavaraja, S, Venkataraman, (2005) A synthesis of MoO3 and its polyvinyl alcohol nanostructured film. Bull Mater Sci 28: pp. 477-481 CrossRef
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Materials Science
  Physical Chemistry
  Condensed Matter
  Renewable Energy Sources
  Electrical Power Generation and Transmission
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1862-0760

文摘

An organic-inorganic composite cation exchanger poly (3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) Zr(IV) phosphate was prepared by the sol-gel method for removal of cadmium, a toxic heavy metal pollutant causing adverse effects on human health. The synthesized material was characterized by various techniques such as thermo gravimetric analysis/differential thermal analysis/differential thermo gravimetry (TGA/DTA/DTG), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). Organic polymer PEDOT:PSS binds with the inorganic counterpart and prevents the leaching of the inorganic parts, hence PEDOT:PSS Zr(IV) phosphate composite cation exchanger has improved ion exchange capacity than inorganic ion exchanger. The composite cation exchanger was found selective towards Cd(II) ions. The nature and composition of contacting solvents influence the selectivity of composite cation exchanger. The composite cation exchanger may be used for the removal of cadmium a toxic heavy metal ion.