Codoping of scandium-containing zirconia-based solid electrolytes with iron, cerium, and copper oxides
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- 作者：O. Z. Yanchevskii ; L. L. Kovalenko ; A. G. Belous
- 关键词：zirconia ; based solid electrolyte ; oxygen ion conductivity ; stabilization of the cubic phase ; scandium oxide ; iron oxide ; ZrO2–CeO2–Sc2O3–Fe2O3 ; Sc2–x Fe x O3
- 刊名：Inorganic Materials
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：52
- 期：3
- 页码：301-308
- 全文大小：933 KB
- 参考文献：1.Striker, D.W. and Carlson, W.G., Electrical conductivity in the ZrO2-Rich region of several M2O3–ZrO2 systems, J. Am. Ceram. Soc., 1965, vol. 48, no. 6, pp. 286–289.CrossRef
2.Badwaal, S.P.S. and Drennan, J., Microstructure/conductivity relationship in the scandia–zirconia system, Solid State Ionics, 1992, vols. 53–56, pp. 769–776.CrossRef
3.Yanchevskii, O.Z., Pashkova, E.V., Ivanitskii, V.P., and Belous, A.G., Mössbauer and X-ray diffraction studies of cubic (ZrO2)0.90(Sc2O3)0.10–x (Fe2O3)x solid solutions, Inorg. Mater., 2012, vol. 48, no. 6, pp. 607–612.CrossRef
4.Breard, Y., Fjellvag, H., and Hauback, B., Investigation of bixbyite type scandium oxides involving a magneticcation: Sc2–x FexO3(0 < x < 1), Solid State Commun., 2011, vol. 151, pp. 223–226.CrossRef
5.Shannon, R.D., Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides, Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr., 1976, vol. 32, no. 5, pp. 751–767.CrossRef
6.Kim, N., Hsieh, C.-H., and Stebbins, J.F., Scandium coordination in solid oxides and stabilized zirconia: 45Sc NMR, Chem. Mater., 2006, vol. 18, pp. 3855–3859.CrossRef
7.Badwaal, S.P.S., Ciacchi, F.T., Rajendran, S., and Drennan, J., An investigation of conductivity, microstructure and stability of electrolyte compositions in the systems 9 mol. %(Sc2O3–Y2O3)–ZrO2(Al2O3), Solid State Ionics, 1998, vol. 109, pp. 167–186.CrossRef
8.Kravchyk, K.V., Belous, A.G., and Pashkova, E.V., Effect of copper oxide on the stabilization and sintering temperature of ZrO2 and Ce–ZrO2, Ukr. Khim. Zh., 2007, vol. 73, no. 11, pp. 26–30.
9.Certificate of Analysis: Standard Reference Material 1976, Instrument Sensitivity Standard for X-Ray Powder Diffraction, Gaitherburg: National Inst. of Standards and Technology, 1991, pp. 1–4.
10.Duran, P., Gonzalez, M., Moure, C., Jurado, J.R., and Paccual, C., A new tentative phase equilibrium diagram for the ZrO2–CeO2 system in air, J. Mater. Sci., 1990, vol. 25, pp. 5001–5006.CrossRef
11.Kosacki, I., Anderson, H.U., Mizutani, Y., and Ukai, K., Nonstoichiometry and electrical transport in Sc-doped zirconia, Solid State Ionics, 2002, vols. 152–153, pp. 431–438.CrossRef
12.Bohnke, O., Gunes, V., Kravchyk, K.V., Belous, A.G., Yanchevskii, O.Z., and V’yunov, O.I., Ionic and electronic conductivity of 3 mol. % Fe2O3-substituted cubic yttria-stabilized ZrO2 (YSZ) or scandia-stabilized ZrO2 (ScSZ), Solid State Ionics, 2013, vol. 262, pp. 517–521.CrossRef
13.Politova, T.I. and Irvine, J.T.S., Investigation of scandia–yttria–zirconia system as an electrolyte material for intermediate temperature fuel cells—influence of yttria content in system (Y2O3)x(Sc2O3)(11–x )(ZrO2)89, Solid State Ionics, 2004, vol. 168, pp. 153–165.CrossRef
14.Kawamura, K., Watanabe, K., Hiramatsu, T., Kaimai, A., Nigara, Y., Kawada, T., and Mizusaki, J., Electrical conductivities of CaO doped ZrO2–CeO2 solid solution system, Solid State Ionics, 2001, vol. 144, pp. 11–18.CrossRef - 作者单位：O. Z. Yanchevskii (1)
L. L. Kovalenko (1)
A. G. Belous (1)
1. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kyiv, 03680, Ukraine - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Inorganic Chemistry
Industrial Chemistry and Chemical Engineering
Materials Science
Russian Library of Science - 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
- ISSN：1608-3172
文摘
Codoping with iron, cerium, and copper oxides has been proposed as a means of improving the performance of scandium-containing zirconia-based solid electrolytes. We have examined three procedures for the synthesis of the (ZrO2)0.825(CeO2)0.07(Sc2O3)0.07(Fe2O3)0.035 solid solution through precipitation from solution. It has been shown that the highest oxygen ion conductivity is ensured by the synthesis procedure that includes the mechanochemical activation of presynthesized scandium ferrate (Sc1.33Fe0.67O3) with cerium and zirconium hydroxides and a solution containing 0.5 mol % Cu.