Determination of the stability constant and thermodynamic parameters between Tl⁺, Ag⁺ and Pb²⁺ cations with 2,6-di(furyl-2yl)-4-(4-methoxy phenyl)pyridine as a new synthesis ligand

详细信息    查看全文

• 作者：Malihe Samadi Kazemi ; Elham Ataeei ; Malihe Nasrabadi
• 关键词：2 ; 6 ; di(furyl ; 2yl) ; 4 ; (4 ; methoxy phenyl)pyridine ; stability constant ; binary solution ; thermodynamic parameters ; heavy metals
• 刊名：Russian Journal of Electrochemistry
• 出版年：2016
• 出版时间：October 2016
• 年：2016
• 卷：52
• 期：10
• 页码：975-982
• 全文大小：497 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3342
• 卷排序：52

文摘

The complexation reaction between Tl+, Ag+ and Pb2+ cations with 2,6-di(furyl-2yl)-4-(4-methoxy phenyl)pyridine as a new synthesis ligand in acetonitrile (ACN)–H₂O and methanol (MeOH)–H₂O binary solutions has been studied at different temperatures using conductometric method. The conductometric data show that the stoichiometry of the complexes is 1: 1 [M: L] and the stability constant of complexes changes with the binary solutions identity. Also, the structure of the resulting 1: 1 complexes was optimized using the LanL2dz basis set at the B3LYP level of theory using GAUSSIAN03 software. The results show that the change of logK_f for (DFMP.Pb)2+ and (DFMP.Ag)+ complexes with the mole ratio of acetonitrile and for (DFMP.Ag)+ and (DFMP.Tl)+ complexes with the mole ratio of methanol have a linear behavior, while the change of logK_f of (DFMP.Tl)+complex in ACN–H₂O binary solutions (with a minimum in X_ACN = 0.5) and (DFMP.Ag)+ complex in MeOH–H₂O binary solutions (with a minimum in X_MeOH = 0.75) show a non-linear behavior. The selectivity order of DFMP ligand for these cations in mol % CAN = 25 and 75 obtain Tl+ > Pb2+ > Ag+ but in mol % CAN = 50, the selectivity order observe Pb2+ > Tl+ > Ag+. Also, this selectivity sequence of DFMP in MeOH–H₂O (mol % MeOH = 75 and 100) and (mol % MeOH = 50) is obtained Pb2+ > Ag+ and Tl+ > Ag+ > Pb2+ respectively. The values of thermodynamic parameters show that these values are influenced by the nature and the composition of binary solution. In all cases, the resulting complexes are enthalpy stabilized and entropy destabilized. The TΔS_C° versus ΔH_C° plot of all obtained thermodynamic data shows a fairly good linear correlation which indicates the existence of enthalpy-entropy compensation in the complexation reactions.