Syntheses, Characterization and Crystal Structures of Diorganotin(IV) Selenites: 1D Helical Double-Chain Containing Eight-Membered Sn2O4Se2 Inorganic Ring

详细信息    查看全文

• 作者：Chunlin Ma (1) macl@lcu.edu.cn
  Jing Ru (1)
  Zhenxing Li (1)
  Rufen Zhang (1)
• 关键词：Diorganotin(IV) selenite – Areneseleninic acid – X ; ray crystallography
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2012
• 出版时间：November 2012
• 年：2012
• 卷：22
• 期：6
• 页码：1287-1292
• 全文大小：556.7 KB
• 参考文献：1. V. Chandrasekhar, V. Baskar, K. Gopal, J.J. Vittal, Organometallics 24, 4926 (2005)
  2. V. Chandrasekhar, S. Nagendran, V. Baskar, Coord. Chem. Rev. 235, 1 (2002)
  3. S.K. Duboy, U. Roy, Appl. Organomet. Chem. 17, 3 (2003)
  4. C.L. Ma, Q. Jiang, R.F. Zhang, Appl. Organomet. Chem. 17, 623 (2003)
  5. G.R. Desiraju, Acc. Chem. Res. 35, 565 (2002)
  6. C.L. Ma, Q.F. Zhang, R.F. Zhang, D.Q. Wang, Chem. Eur. J. 12, 420 (2006)
  7. W.T. Piver, Environ. Health Perspect. 4, 61 (1973)
  8. V. Chandrasekhar, M.G. Muralidhara, K.R. Justin Thomas, E.R.T. Tiekink, Inorg. Chem. 31, 4707 (1992)
  9. A.J. Mukherjee, S.S. Zade, H.B. Singh, R.B. Sunoj, Chem. Rev. 110, 4351 (2010)
  10. K.P. Bhabak, G. Mugesh, Acc. Chem. Res. 43, 1408 (2010)
  11. H.J. Thompson, A. Wilson, J. Lu, M. Singh, C. Jiang, P. Upadhyaya, K. El-Bayoumy, Carcinogenesis 15, 183 (1994)
  12. C.L. Ma, M.J. Guo, J. Ru, Q.F. Wang, R.F. Zhang, Inorg. Chim. Acta 378, 315 (2011)
  13. R.F. Zhang, J. Ru, Z.X. Li, C.L. Ma, J.P. Zhang, J. Coord. Chem. 64, 4122 (2011)
  14. J. Ru, R.F. Zhang, Acta. Cryst. E67, m1809 (2011)
  15. S.L. Zheng, P.L. Xu, J. WCUMS 26, 371 (1995)
  16. J. Hole?ek, M. Nadvornik, K. Handlí?, A. Ly?ka, J. Organomet. Chem. 315, 299 (1986)
  17. G.M. Sheldrick, SHELXL-97, Program for Structure Solution (University of G?ttingen, Germany, 1997)
  18. A. Bondi, J. Phys. Chem. 68, 441 (1964)
  19. A.-F. Shihada, Z Anorg. Allg. Chem. 632, 2238 (2006)
  20. C.L. Ma, J.S. Sun, R.F. Zhang, Inorg. Chim. Acta 359, 4179 (2006)
  21. C.L. Ma, Q.F. Zhang, R.F. Zhang, L.L. Qiu, J. Organomet. Chem. 690, 3033 (2005)
  22. C.L. Ma, G.R. Tian, R.F. Zhang, Inorg. Chem. Commun. 9, 882 (2006)
• 作者单位：1. Department of Chemistry, Liaocheng University, Liaocheng, 252059 People’s Republic of China
• ISSN：1574-1451

文摘

Three new diorganotin(IV) selenites, [Bu₂Sn(O₂SeC₆H₅OMe)₂]_n (1), [Me₂Sn(O₂SeC₆H₄CHMe₂)₂]_n (2), [Me₂Sn(O₂SeC₆H₄Et)₂]_n (3) have been synthesized and structurally characterized by elemental analysis, FT-IR, NMR (1H, 13C and 119Sn) spectra, TGA, and X-ray crystallography. The X-ray reveals that complexes 1–3 are 1D infinite double-chain polymers. The molecular of complex 1 is further linked by intermolecular C–H···O interactions to form a 2D network polymer. Complex 3 is linked by C–H···O interactions to form a 3D organotin framework.