Triphenylamine-based electroactive compounds: synthesis, properties and application to organic electronics
详细信息 查看全文
- 作者：Renata Rybakiewicz ; Malgorzata Zagorska ; Adam Pron
- 关键词：Triphenylamine ; Conjugated polymers ; Organic semiconductors ; Organic electronics
- 刊名：Chemical Papers
- 出版年：2017
- 出版时间：February 2017
- 年：2017
- 卷：71
- 期：2
- 页码：243-268
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering; Biochemistry, general; Medicinal Chemistry; Materials Science, general; Biotechnology;
- 出版者：Springer International Publishing
- ISSN：1336-9075
- 卷排序：71
文摘
This review is devoted to low and high molecular mass electroactive materials containing triphenylamine (TPA) structural units. It is shown that by appropriate selection of C–C coupling methods, it is possible to obtain solution-processable, electroactive materials of tunable donor–acceptor properties, suitable for the use as active layers in p-channel or ambipolar field effect transistors, as hole-transporting layers and as electroluminophores in organic light-emitting diodes. Other applications involve their use as components of bulk heterojunctions in organic solar cells and dye-sensitized solar cells. Since TPA-based materials exhibit high electrochemical reversibility, they can also be technologically exploited as solution-processable electrochromic materials.