Oxidation of d-Glucose by Silver(III) Periodate Complex in the Presence of Ru(III)/Os(VIII) as a Homogeneous Catalyst: A Comparative Mechanistic Study (Stopped Flow Technique)
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- 作者：Sanjeevaraddi R. Sataraddi (1)
Sharanappa T. Nandibewoor (1) - 关键词：Oxidation ; Kinetics ; d ; Glucose ; Silver(III) periodate complex ; Os(VIII) catalyst ; Ru(III) catalyst
- 刊名：Journal of Solution Chemistry
- 出版年：2013
- 出版时间：June 2013
- 年：2013
- 卷：42
- 期：5
- 页码：897-915
- 全文大小：536KB
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Sharanappa T. Nandibewoor (1)
1. P. G. Department of Studies in Chemistry, Karnatak University, Dharwad, 580003, India - ISSN：1572-8927
文摘
The kinetics of the oxidation of ruthenium(III) (Ru(III)) and osmium(VIII) (Os(VIII)) catalyzed oxidation of d-glucose (d-Glu) by silver(III) periodate complex (DPA) in aqueous alkaline medium at 298?K and constant ionic strength 0.003?mol·dm? was studied spectrophotometrically. The reaction between d-Glu and DPA in alkaline medium exhibits 1:2 stoichiometry in both catalyzed reactions (d-Glu:DPA). The main products were identified as D-arabinonic acid and formic acid by spot tests, GC–MS spectra and chromatographic techniques. The reaction orders with respect to various species concentrations were determined. Also, the active species of catalyst and oxidant have been identified. Probable mechanisms were proposed. The activation parameters with respect to the slow step of the mechanism were computed and discussed and thermodynamic quantities were also calculated. It has been observed that the catalytic efficiency for the present reaction is in the order Os(VIII)?>?Ru(III).