Effect of reactant association on addition of tertiary amines to acrylic acid in aqueous solutions
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- 作者：A. P. Malyshev ; K. V. Shirshin ; O. A. Kazantsev ; A. P. Sivokhin ; I. V. Zhiganov and A. E. Kuznetsov
- 刊名：Russian Journal of Applied Chemistry
- 出版年：2006
- 出版时间：October, 2006
- 年：2006
- 卷：79
- 期：10
- 页码：1629-1633
- 全文大小：141 KB
文摘
The formation of betaines by the reaction of tertairy amines (N,N-dimethyl-N-2-hydroxyethylamine, N,N-dimethylaminoethyl methacrylate, N-methylmorpholine, N,N-dimethylaminopropionitrile, 1,4-diazabicyclo[2.2.2]octane) with acrylic acid in aqueous solutions in a wide concentration range was studied. The concentration effects observed were interpreted taking into account the association of the starting reagents.