Effect of reactant association on addition of tertiary amines to acrylic acid in aqueous solutions

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• 作者：A. P. Malyshev ; K. V. Shirshin ; O. A. Kazantsev ; A. P. Sivokhin ; I. V. Zhiganov and A. E. Kuznetsov
• 刊名：Russian Journal of Applied Chemistry
• 出版年：2006
• 出版时间：October, 2006
• 年：2006
• 卷：79
• 期：10
• 页码：1629-1633
• 全文大小：141 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Industrial Chemistry and Chemical Engineering
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3296

文摘

The formation of betaines by the reaction of tertairy amines (N,N-dimethyl-N-2-hydroxyethylamine, N,N-dimethylaminoethyl methacrylate, N-methylmorpholine, N,N-dimethylaminopropionitrile, 1,4-diazabicyclo[2.2.2]octane) with acrylic acid in aqueous solutions in a wide concentration range was studied. The concentration effects observed were interpreted taking into account the association of the starting reagents.