Destruction of representative submarine food waste using supercritical water oxidation
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  • 作者:Shiying Chen ; Xuan Qu ; Rong Zhang
  • 关键词:Supercritical water oxidation ; Food waste ; Submarine ; Kinetics modeling ; Water recycling
  • 刊名:Environmental Science and Pollution Research
  • 出版年:2015
  • 出版时间:March 2015
  • 年:2015
  • 卷:22
  • 期:6
  • 页码:4527-4533
  • 全文大小:630 KB
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  • 刊物类别:Earth and Environmental Science
  • 刊物主题:Environment
    Environment
    Atmospheric Protection, Air Quality Control and Air Pollution
    Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
    Industrial Pollution Prevention
  • 出版者:Springer Berlin / Heidelberg
  • ISSN:1614-7499
文摘
In this study, 13 types of organic materials were oxidized using H2O2 in a continuous flow reactor under the condition of supercritical water. The effect of the operational parameters on the conversion of total organic carbon (TOC) and total nitrogen (TN) was investigated, and the resulting quality of treated water was analyzed. It was found that these materials were easily oxidized with a TOC conversion achieving 99?% at temperature of 460?°C and TN conversion reaching 94?% at temperature of 500?°C. Rice decomposition was rapid, with TOC and TN decomposition rates of 99?% obtained within residence of 100?s at temperature of 460?°C. At temperature of 460?°C, pressure of 24?MPa, residence time of 100?s, and excess oxygen of 100?%, the quality of treated water attained levels commensurate with China’s Standards for Drinking Water Quality. Reaction rate equation parameters were obtained by fitting the experimental data to the differential equation obtained using the Runge–Kutta algorithm. The decrease of the TOC in water samples exhibited reaction orders of 0.95 for the TOC concentration and 0.628 for the oxygen concentration. The activation energy was 83.018?kJ/mol.

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