Highly efficient reduction of tertiary phosphine oxides and sulfides with amine-assisted aluminum hydrides under mild conditions

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• 作者：Shuyan Yang ; Xinxin Han ; Minmin Luo ; Jing Gao…
• 关键词：reduction reaction ; amine ; assisted ; phosphides ; aluminum hydrides
• 刊名：Russian Journal of General Chemistry
• 出版年：2015
• 出版时间：May 2015
• 年：2015
• 卷：85
• 期：5
• 页码：1156-1160
• 全文大小：149 KB
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• 作者单位：Shuyan Yang (1)
  Xinxin Han (1)
  Minmin Luo (1)
  Jing Gao (1)
  Wenxiang Chu (1)
  Yuqiang Ding (1)
  
  1. The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, Jiangsu Province, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3350

文摘

Reduction of tertiary phosphine oxides and sulfides into the corresponding phosphines with amine-assisted aluminum hydrides has been studied. The method is characterized by mild conditions, short reaction time, high efficiency, and expanded substrate scope. The new method is an alternative to the currently used methods of reducing phosphine oxides or recycling phosphines engaged in organic reactions.