Control of phase composition of silver iodide by mechanoactivation

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• 作者：V. V. Tomaev ; Yu. S. Tver’yanovich ; M. D. Bal’makov…
• 关键词：silver iodide ; silver halide ; nanoparticle ; stable and metastable phases ; superionic ; ionic conductivity ; mechanomodification
• 刊名：Glass Physics and Chemistry
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：41
• 期：6
• 页码：637-642
• 全文大小：4,113 KB
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• 作者单位：V. V. Tomaev (1)
  Yu. S. Tver’yanovich (1)
  M. D. Bal’makov (1)
  I. A. Zvereva (1)
  
  1. Chemical Institute, St. Petersburg State University, Universitskii pr. 26, Peterhof, St. Petersburg, 198504, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Ceramics,Glass,Composites,Natural Materials
  Characterization and Evaluation Materials
  Materials Science
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-313X

文摘

The features of mechanochemical synthesis and the criteria for assessing the role of the random factor in the formation of nanosystems have been considered. The phase composition of nanostructured silver iodide is controlled by mechanomodification. Particular attention is paid to the control entropy, characterizing the role of the random factor in the process of the synthesis of nanosystems. The surface morphology of the obtained samples has been studied by scanning electron microscopy. The phase composition has been determined by X-ray analysis. Keywords silver iodide silver halide nanoparticle stable and metastable phases superionic ionic conductivity mechanomodification