Multistimuli-responsive hydrogels of poly(2-acrylamido-2-methyl-1-propanesulfonic acid) containing graphene
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  • 作者:Valeria Alzari (1)
    Daniele Nuvoli (1)
    Roberta Sanna (1)
    Laura Peponi (2)
    Massimo Piccinini (3)
    Silvia Bittolo Bon (4)
    Salvatore Marceddu (5)
    Luca Valentini (4)
    Jose Maria Kenny (2)
    Alberto Mariani (1)
  • 关键词:Hydrogels ; Nanocomposites ; Polyelectrolytes ; Stimuli ; sensitive polymers ; Swelling
  • 刊名:Colloid & Polymer Science
  • 出版年:2013
  • 出版时间:November 2013
  • 年:2013
  • 卷:291
  • 期:11
  • 页码:2681-2687
  • 全文大小:295KB
  • 参考文献:1. Kim SJ, Lee CK, Kim SI (2004) Electrical/pH responsive properties of poly(2-acrylamido-2-methylpropane sulfonic acid)/hyaluronic acid hydrogels. J Appl Pol Sci 92:1731鈥?736 CrossRef
    2. Gil ES, Hudson SM (2004) Stimuli-responsive polymers and their bioconjugates. Prog Polym Sci 29:1173鈥?222 CrossRef
    3. Melekaslan D, Okay O (2000) Swelling of strong polyelectrolyte hydrogels in polymer solutions: effect of ion pair formation on the polymer collapse. Polymer 41:5737鈥?747 CrossRef
    4. Otake M, Kayami Y, Inaba M, Inoue H (2002) Motion design of a starfish-shaped gel robot made of electro-active polymer gel. Robot Auton Syst 40:185鈥?91 CrossRef
    5. Kabiri K, Zohuriaan-Mehr MJ, Mirzadeh H, Kheirabadi M (2010) Solvent-, ion- and pH-specific swelling of poly(2-acrylamido-2-methylpropane sulfonic acid) superabsorbing gels. J Polym Res 17(203):212
    6. Durmaz S, Okay O (2000) Acrylamide/2-acrylamido-2-methyl propane sulfonic acid sodium salt-based hydrogels: synthesis and characterization. Polymer 41:3693鈥?704 CrossRef
    7. Ozmen MM, Okay O (2005) Superfast responsive ionic hydrogels with controllable pore size. Polymer 46:8119鈥?127 CrossRef
    8. Wang KH, Choi MH, Koo CM, Choi YS, Chung IJ (2001) Synthesis and characterization of maleated polyethylene/clay nanocomposites. Polymer 42:9819鈥?826 CrossRef
    9. Cavus S, Gurdag G (2009) Noncompetitive removal of heavy metal ions from aqueous solutions by poly[2-(acrylamido)-2-methyl-1-propanesulfonic acid-co-itaconic acid] hydrogel. Ind Eng Chem Res 48:2652鈥?658 CrossRef
    10. Kajiwara K, Ross-Murphy SB (1992) Synthetic gels on the move. Nature 355:208鈥?09 CrossRef
    11. El-Hag AA, Abd El Rehim HA, Hegazy EA, Ghobashy MM (2006) Synthesis and electrical response of acrylic acid/vinyl sulfonic acid hydrogels prepared by 纬-irradiation. Radiat Phys Chem 75:1041鈥?046 CrossRef
    12. Yoshida R, Sakai K, Okano T, Sakurai Y (1993) Modern hydrogel delivery systems. Adv Drug Deliv Rev 11:85鈥?08 CrossRef
    13. Sawahata K, Hara M, Yasunaga H, Osada Y (1990) Electrically controlled drug delivery system using polyelectrolyte gels. J Control Release 14:253鈥?62 CrossRef
    14. Kwon IC, Bae YH, Okano T, Kim SW (1991) Drug release from electric current sensitive hydrogels. J Control Release 17:149鈥?56 CrossRef
    15. Kabiri K, Mirzade H, Zohuriaan-Meh MJ, Dalir M (2009) Chitosan-modified nanoclay鈥損oly(AMPS) nanocomposite hydrogels with improved gel strength. Polym Int 58:1252鈥?259 CrossRef
    16. Haraguchi K, Farnworth R, Ohbayashi A, Takehisa T (2003) Compositional effects on mechanical properties of nanocomposite hydrogels composed of poly (N, N-dimethylacrylamide) and clay. Macromolecules 36:5732鈥?741 CrossRef
    17. Alzari V, Mariani A, Monticelli O, Valentini L, Nuvoli D, Piccinini M, Scognamillo S, Bittolo Bon S, Illescas J (2010) Stimuli-responsive polymer hydrogels containing partially exfoliated graphite. J. Polym Sci Par A: Pol Chem 48:5375鈥?381 CrossRef
    18. Alzari V, Nuvoli D, Scognamillo S, Piccinini M, Gioffredi E, Malucelli G, Marceddu S, Sechi M, Sanna V, Mariani A (2011) Graphene-containing nanocomposite hydrogels of poly( / N-isopropylacrylamide) prepared by frontal polymerization. J Mater Chem 21:8727鈥?733 CrossRef
    19. Balandin AA, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F, Lau CN (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8:902鈥?07 CrossRef
    20. Bolotin KI, Sikes KJ, Jiang Z, Klima M, Fudenberg G, Hone J, Kim P, Stormer HL (2008) Ultrahigh electron mobility in suspended graphene. Solid State Commun 146:351鈥?55 CrossRef
    21. Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8:3498鈥?502 CrossRef
    22. Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321:385鈥?88 CrossRef
    23. Nuvoli D, Valentini L, Alzari V, Scognamillo S, Bittolo Bon S, Piccinini M, Illescas J, Mariani A (2011) High concentration few-layer graphene sheets obtained by liquid phase exfoliation of graphite in ionic liquid. J Mater Chem 21(3428):3431
    24. Scognamillo S, Gioffredi E, Piccinini M, Lazzari M, Alzari V, Nuvoli D, Sanna R, Piga D, Malucelli G, Mariani A (2012) Synthesis and characterization of nanocomposites of thermoplastic polyurethane with both graphene and graphene nanoribbon fillers. Polymer 53:4019鈥?024 CrossRef
    25. Alzari V, Nuvoli D, Sanna R, Scognamillo S, Piccinini M, Kenny JM, Malucelli G, Mariani A (2011) In situ production of high filler content graphene-based polymer nanocomposites by reactive processing. J Mater Chem 21:16544鈥?6549 CrossRef
    26. Sanna R, Sanna D, Alzari V, Nuvoli D, Scognamillo S, Piccinini M, Lazzari M, Gioffredi E, Malucelli G, Mariani A (2012) Synthesis and characterization of graphene-containing thermoresponsive nanocomposite hydrogels of poly( / N-vinylcaprolactam) prepared by frontal polymerization. J Polym Sci Part A: Pol Chem 50:4110鈥?118 CrossRef
    27. Hernandez Y, Nicolosi V, Lotya M, Blighe FM, Sun ZY, De S, McGovern IT, Holland B, Byrne M, Gun'ko YK, Boland JJ, Niraj P, Duesberg G, Krishnamurthy S, Goodhue R, Hutchison J, Scardaci V, Ferrari AC, Coleman JN (2008) High-yield production of graphene by liquid-phase exfoliation of graphite. Nat Nanotechnol 3:563鈥?68 CrossRef
    28. Mariani A, Nuvoli D, Alzari V, Pini M (2008) Phosphonium-based ionic liquids as a new class of radical initiators and their use in gas-free frontal polymerization. Macromolecules 41:5191鈥?196 CrossRef
    29. Lotya M, Hernandez Y, King PJ, Smith RJ, Nicolosi V, Karlsson LS, Blighe FM, De S, Wang Z, McGovern IT, Duesberg GS, Coleman JN (2009) Exfoliation of graphite in surfactant/water solutions. J Am Chem Soc 131:3611鈥?620 CrossRef
    30. Ferrari AC, Meyer JC, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov KS, Roth S, Geim AK (2006) The Raman fingerprint of graphene. Phys Rev Lett 97(187401):1鈥?
    31. Ferrari AC (2007) Raman spectroscopy of graphene and graphite: disorder, electron鈥損honon coupling, doping and nonadiabatic effects. Solid State Commun 143:47鈥?7 CrossRef
    32. Lotya M, King PJ, Khan U, De S, Coleman JN (2010) High-concentration, surfactant-stabilized graphene dispersions. ACS Nano 4:3155鈥?2 CrossRef
    33. Casiraghi C, Hartschuh A, Qian H, Piscanec S, Georgi C, Fasoli A, Novoselov KS, Basko DM, Ferrari AC (2009) Raman spectroscopy of graphene edges. Nano Lett 9:1433鈥?1 CrossRef
    34. Khan U, O'Neill A, Lotya M, De S, Coleman JN (2010) High-concentration solvent exfoliation of graphene. Small 6(7):864鈥?71 CrossRef
    35. Lai F, Li H (2010) Transient modeling for kinetic swelling/deswelling of the ionic-strength-sensitive hydrogel. Eur Phys J E 31:269鈥?74 CrossRef
    36. Murdan S (2003) Electro-responsive drug delivery from hydrogels. J Control Release 92:1鈥?7 CrossRef
    37. Wang Z, Nelson JK, Hillborg H, Zhao S, Schadler LS (2012) Graphene oxide filled nanocomposite with novel electrical and dielectric properties. Adv Mater 24:3134鈥?137 CrossRef
  • 作者单位:Valeria Alzari (1)
    Daniele Nuvoli (1)
    Roberta Sanna (1)
    Laura Peponi (2)
    Massimo Piccinini (3)
    Silvia Bittolo Bon (4)
    Salvatore Marceddu (5)
    Luca Valentini (4)
    Jose Maria Kenny (2)
    Alberto Mariani (1)

    1. Dipartimento di Chimica e Farmacia, Universit脿 degli Studi di Sassari e Unit脿 locale INSTM, Via Vienna 2, 07100, Sassari, Italy
    2. Institute of Polymer Science and Technology (ICTP-CSIC), Calle Juan de la Cierva 3, 28006, Madrid, Spain
    3. Porto Conte Ricerche S.r.l., SP 55 km 8.400 Loc., Tramariglio, 07041, Alghero (SS), Italy
    4. Civil and Environmental Engineering Department, INSTM Research Unit, University of Perugia, Strada di Pentima 4, 05100, Terni, Italy
    5. Consiglio Nazionale delle Ricerche (CNR), Istituto di Scienze delle Produzioni Alimentari (ISPA), Li Punti (Reg. Baldinca), Traversa La Crucca, 07100, Sassari, Italy
  • ISSN:1435-1536
文摘
Nanocomposite hydrogels of poly(2-acrylamido-2-methyl-1-propanesulfonic acid) containing graphene were prepared by radical polymerization. Their swelling properties in response to ionic strength and electrical stimuli were assessed. Graphene was obtained through an easy and convenient method lately developed by our research group, which consists in the exfoliation of graphite by sonicating it in a proper solvent medium. It was found that the graphene content influences the swelling properties of hydrogels; in particular, those containing graphene swell more than the filler-free ones; graphene content influences also the swelling ratio variation between the swollen and deswollen states.

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