Synthesis and catalytic activity of N-heterocyclic carbene metal carbonyl complexes based on 1-[2-(pyrazol-1-yl)phenyl]imidazole

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• 作者：Cai-Hong Cheng (1)
  Ren-Yu Guo (1)
  Qi Cui (1)
  Hai-Bin Song (1)
  Liang-Fu Tang (1)
  
  1. Department of Chemistry ; State Key Laboratory of Elemento-Organic Chemistry ; Nankai University ; Tianjin ; 300071 ; People鈥檚 Republic of China
  
• 刊名：Transition Metal Chemistry
• 出版年：2015
• 出版时间：April 2015
• 年：2015
• 卷：40
• 期：3
• 页码：297-304
• 全文大小：749 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-901X

文摘

A series of N-heterocyclic carbene transition metal (molybdenum, tungsten and ruthenium) carbonyl complexes derived from 1-[2-(pyrazol-1-yl)phenyl]-imidazole have been synthesized and characterized by physico-chemical and spectroscopic methods, and the structures of five complexes have been confirmed by X-ray crystal structure analyses. The azaaryl-functionalized N-heterocyclic carbenes act as chelating N,C-bidentate ligands in these five complexes. Preliminary catalytic tests of these NHC-molybdenum (tungsten) carbonyl complexes in the oxidation of styrene have been carried out, showing that benzaldehyde was the main oxidation product when hydrogen peroxide was used as the oxidant, while 2,5-diphenyl-1,4-dioxane was obtained as the exclusive product in the oxidation by tert-butyl hydroperoxide.