Preparation, Characterization and Properties of Novel Cationic Gemini Surfactants with Rigid Amido Spacer Groups

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• 作者：Dongqing Xu ; Banghua Qi ; Di Fang ; Xuemei Zhang…
• 关键词：Gemini surfactants ; Rigid amido spacer groups ; Surface activity properties ; Synthesis
• 刊名：Journal of Surfactants and Detergents
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：19
• 期：1
• 页码：91-99
• 全文大小：522 KB
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• 作者单位：Dongqing Xu (1)
  Banghua Qi (1)
  Di Fang (2)
  Xuemei Zhang (2)
  Ting Zhang (2)
  
  1. Center of Analysis and Measurement, Anhui Science and Technology University, Fengyang, Anhui, 233100, China
  2. School of Chemistry and Material Engineering, Anhui Science and Technology University, Fengyang, Anhui, 233100, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Surfaces and Interfaces and Thin Films
  Polymer Sciences
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Analytical Chemistry
  Physical Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1558-9293

文摘

A series of novel cationic gemini surfactants with rigid amido groups inserted as the spacers, named C ₁₂ -PPDA-C ₁₂ , C ₁₄ -PPDA-C ₁₄ and C ₁₆ -PPDA-C ₁₆ , were synthesized by a two-step reaction with dimethyl terephthalate, N,N-dimethyl propylene diamine and alkyl bromide as raw materials. The chemical structures of the prepared compounds were confirmed by IR, 1H and 13C NMR and element analysis. Surface activity properties of the synthesized compounds were investigated by surface tension, electrical conductivity and fluorescence. Increasing the number of carbon atoms in the hydrophobic alkyl chain, decreased the critical micelle concentration (CMC), surface tension at the CMC and the minimum surface area. Other relevant properties including foaming ability and emulsion stability were investigated. The results indicated that the synthesized gemini surfactants possess good surface properties, emulsifying properties and steady foam properties.