刊名:Russian Journal of Physical Chemistry B, Focus on Physics
出版年:2015
出版时间:July 2015
年:2015
卷:9
期:4
页码:558-560
全文大小:309 KB
参考文献:1.I. Noda and Y. Ozaki, Two-Dimensional Correlation Spectroscopy-Applications in Vibrational and Optical Spectroscopy (Wiley, UK, 2004).CrossRef 2.I. Noda, Bull. Am. Phys. Soc., No. 31, 520 (1986). 3.A. Likar and T. Vidmar, J. Phys. D: Appl. Phys., No. 36, 1903 (2003).CrossRef 4.M. A. Mariscotti, Nucl. Instrum. Methods Phys. Res., No. 50, 309 (1967).CrossRef 5.Shigeaki Morita, 2D-shige (Kwansei-Gakuin Univ., 2004-006). http://?ksc-new-dep.?sakura.?ne.?jp/?ozakilabo/?treasure/-d-shige/-/cite>
作者单位:E. A. Maksimova (1) S. F. Bureiko (1) S. B. Levin (1) L. M. Derzhavets (1)
1. Saint Petersburg State University, Ulianovskaya Str. 3 Russian Federation, Petrodvorets, 198504, Saint Petersburg, Russia
刊物类别:Chemistry and Materials Science
刊物主题:Chemistry Physical Chemistry Russian Library of Science
出版者:MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
ISSN:1990-7923
文摘
In this work a two-dimensional correlation spectroscopy method is extended using a continuous two-dimensional spectral surface approximation. The paper presents the results of calculating of the correlation spectra for ozonolysis ethylene reaction at constant temperature. A new method for peaks searching in the 1D spectrum was developed to improve the quality of calculations. In contrast to the Noda’s theory [1] on asynchronous spectrum, the one peak corresponding to secondary ozonide indicating on the certain sequence of events in the reaction is found. The advantage of our technique is the continuity of the function approximating the spectrum. Keywords correlation spectroscopy wavelet analysis sequence of events peak search IR spectra ozonolysis