Evaluation of soil amendments as a remediation alternative for cadmium-contaminated soils under cacao plantations
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  • 作者:E. Chavez ; Z. L. He ; P. J. Stoffella…
  • 关键词:Cacao ; growing soils ; Plant ; available Cd ; Single extraction ; Vermicompost ; Zeolite
  • 刊名:Environmental Science and Pollution Research
  • 出版年:2016
  • 出版时间:September 2016
  • 年:2016
  • 卷:23
  • 期:17
  • 页码:17571-17580
  • 全文大小:981 KB
  • 刊物类别:Earth and Environmental Science
  • 刊物主题:Environment
    Environment
    Atmospheric Protection, Air Quality Control and Air Pollution
    Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
    Industrial Pollution Prevention
  • 出版者:Springer Berlin / Heidelberg
  • ISSN:1614-7499
  • 卷排序:23
文摘
Elevated plant-available cadmium (Cd) in soils results in contamination to cacao (Theobroma cacao L) beans. Effectiveness of vermicompost and zeolite in reducing available Cd in three cacao-growing soils was studied under laboratory conditions. Sorption–desorption experiments were conducted in soils and amendments. Cadmium was added at 0 or 5 mg kg−1 (spiked), then, amendments were incorporated at 0, 0.5, or 2 %. Amended soils were incubated at room temperature for 28 days. Plant-available Cd was determined using 0.01 M CaCl2 (WSE) and Mehlich 3 (M3) extraction procedures in subsamples taken from individual bags at six time intervals. Soils and amendments displayed different sorption characteristics and a better fit was attained with Freundlich model (R2 > 0.82). Amendments were ineffective in reducing extractable Cd in non-spiked soils. In Cd-spiked soils, vermicompost at 2 % significantly reduced WSE-Cd (P < 0.01) from 3.36, 0.54, and 0.38 mg kg−1 to values lower that instrument’s detection in all the three soils and significantly diminished M3-extractable Cd (P < 0.05) from 4.62 to 4.11 mg kg−1 in only one soil. Vermicompost at 0.5 % significantly decreased WSE-Cd (P < 0.01) from 3.04 and 0.31 to 1.69 and 0.20 mg kg−1, respectively, in two soils with low sorption capacity for Cd. In contrast, zeolite failed to reduce WSE- or M3-extractable Cd in all studied soils. A negative correlation occurred between soil pH and WSE-Cd (r > −0.89, P < 0.01). The decrease in WSE-Cd appears to be associated with the increase in pH of the vermicompost-amended soils.

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