Structure Design and Crystal Growth of UV Nonlinear Borate Materials

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• 作者：Ning Ye (1) nye@fjirsm.ac.cn
• 关键词：Borate &#8211 ; Nonlinear optical crystal &#8211 ; Structure design
• 刊名：Structure & Bonding
• 出版年：2012
• 出版时间：2012
• 年：2012
• 卷：144
• 期：1
• 页码：181-221
• 全文大小：1.9 MB
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• 作者单位：1. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, People鈥檚 Republic of China
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1616-8550

文摘

Crystal design and growth of huntite-type and alkaline beryllium borates used for UV and deep-UV frequency conversion are summarized. A series borates crystallizing in the trigonal-huntite structure, ReM₃(BO₃)₄ (Re = La, Ga, Y, Lu; M = Y, Lu, Sc, Ga, Al), has been discovered through structural design with respect to the size tuning on trigonal prism or/and octahedral site in the structure. The structural, optical, and chemical–physical properties are detailed. They all have large NLO coefficients, moderate birefringence for UV phase matching, and robust chemical and physical properties. The NLO coefficients of those containing Bi are larger due to the contribution from the lone-pair electron of Bi, while the UV cutoff of these crystals is redshift for about 100 nm. The systematical synthesis of a series of new alkaline beryllium borates with the stoichiometry NaBeB₃O₆, ABe₂B₃O₇ (A = K, Rb), and Na₂CsBe₆B₅O₁₅ in order to obtain deep-UV NLO crystals containing new beryllium borate anionic groups or framework was presented. A new beryllium borate anionic group [Be₂B₃O₁₁]9− was found in the structure of NaBeB₃O₆ and α-KBe₂B₃O₇. β-KBe₂B₃O₇, γ-KBe₂B₃O₇, RbBe₂B₃O₇, and Na₂CsBe₆B₅O₁₅ consist of 2D alveolate beryllium borate network [Be₂BO₅]_∞. Furthermore, the adjacent [Be₂BO₅]_∞ layers in these compounds were connected by covalent bonds.