Energetic Cuprous Azide Complex: Synthesis, Crystal Structure and Effection on the Thermal Decomposition of HMX

详细信息    查看全文

• 作者：Fan Guang (1) fanguang2004@163.com
  Zhang Yin-li (1)
  Zheng Min-yan (1)
  Sun Jia-juan (1)
• 关键词：Energetic complex &#8211 ; Cuprous azide &#8211 ; Crystal structure &#8211 ; Catalysis action
• 刊名：Journal of Chemical Crystallography
• 出版年：2012
• 出版时间：September 2012
• 年：2012
• 卷：42
• 期：9
• 页码：923-927
• 全文大小：311.8 KB
• 参考文献：1. Chavez DE, Hiskey MA, Gilardi RD (2000) Angew Chem Int Ed 39:1791–1794
  2. Zhang GF, Wang Y, Cai MY, Dai DM, Yan K, Ma AS, Chen P, Wang R, Li P, Yi JH, Zhao FQ, Li JZ, Fan XZ (2010) J Coord Chem 63:1480–1491
  3. Singh G, Felix SP (2002) J Hazard Mater 90:1–17
  4. Feng JL, Zhang JG, Li ZM, Zhang TL, Cui Y, Yang L (2010) Acta Chim Sinica 68:2493–2499
  5. Cui Y, Zhang JG, Zhang TL, Yang L, Zhang J, Hu XC (2008) J Hazard Mater 160:45–50
  6. Jiao BJ, Chen SP, Zhao FQ, Hu RZ, Gao SL (2007) J Hazard Mater 142:550–554
  7. Zhu W, Xiao H (2006) J Phys Chem B 110:18196–18204
  8. Huynh MHV, Hiskey MA, Meyer TJ, Wetzler M (2006) Proc Natl Acad Sci USA 103:5409
  9. Cartwright M, Wilkinson J (2010) Propellants Explos Pyrotech 35:326–332
  10. Evans BL, Yoffe AD, Gray P (1959) Chem Rev 59:515–529
  11. Pelletier V, Bhattacharyya S, Knoke I, Forohar F, Bichay M, Gogotsi Y (2010) Adv Funct Mater 20:3168–3174
  12. Mautner FA, Cortes R, Lezama L, Rojo T (1996) Angew Chem Int Ed 35:78–80
  13. Escuer A, Vicente R, Fallah MSE, Goher MAS, Mautner FA (1998) Inorg Chem 37:4466–4469
  14. Aebersold MA, Gillon B, Plantevin O, Pardi L, Kahn O, Ergerat P, Seggern I, Tuczek F, Grand A, Lelievre BE (1998) J Am Chem Soc 120:523–526
  15. Zhang L, Tang LF, Wang ZH, Du M, Julve M, Lloret F, Wang JT (2001) Inorg Chem 40:3619–3622
  16. Fan G, Chen S, Gao S (2007) Struct Chem 18:725–731
  17. Adhikary C, Koner S (2010) Coord Chem Rev 254:2933–2958
  18. Mohamed AA (2010) Coord Chem Rev 254:1918–1947
  19. Sheldrick GM (1997) SHELXS-97, Program for Crystal Structure Solution. University of G枚ttingen, G枚ttingen
  20. Sheldrick GM (1997) SHELXL-97, Program for Crystal Structure Refinement. University of G枚ttingen, G枚ttingen
  21. Chambers C, Holliday AK (1975) Mordern Inorganic Chemistry. Butterworths & Co Ltd, London
  22. Jiang M, Li YT, Wu ZY, Yin ZW (2009) J Coord Chem 62:380–389
  23. Li H, Sun TT, Zhang SG, Shi JM (2010) J Coord Chem 63:1531–1537
  24. Li JM, Jin X (2009) J Coord Chem 62:2610–2615
  25. Koehler J, Meyer R (1998) Explosivstoffe, 9th edn. Wiley-VCH, Weinheim
  26. Anniyappan M, Stalwart MB, Gore GM, Venugopalan S, Gandhe BR (2006) J Hazard Mater B137:812–819
  27. Wei ZX, Xu YQ, Liu HY, Hu CW (2009) J Hazard Mater 165:1056–1061
• 作者单位：1. College of Chemistry & Chemical Engineering, Xianyang Normal University, Xianyang, 712000 Shaanxi, China
• ISSN：1572-8854

文摘

Abstract A novel energetic cuprous azide complex with the formula of [Cu₂(dmpyz)(N₃)₂] _n (1) (dmpyz: 2,5-dimethylpyrazine) has been synthesized through hydrothermal method by utilizing the reducibility of H₃PO₃ and structurally characterized by X-ray single crystal diffraction method. Single crystal X-ray diffraction analysis reveals complex (1) featuring a two-dimensional layer structure constructed from copper(I) atoms bridged by azide anion and further connected by pyrazine ligand to form a 3D network. The result of catalysis research reveals it can promote the burning rate of main component of rocket propellants.