Effective conversion of maize straw wastes into bio-hydrogen by two-stage process integrating H2 fermentation and MECs
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  • 作者:Yan-Hong Li ; Yan-Xia Bai ; Chun-Mei Pan…
  • 关键词:Maize straw ; Subcritical water hydrolysis ; Bio ; hydrogen production ; Hydrogen fermentation ; Microbial electrolysis cells (MECs)
  • 刊名:Environmental Science and Pollution Research
  • 出版年:2015
  • 出版时间:December 2015
  • 年:2015
  • 卷:22
  • 期:23
  • 页码:18394-18403
  • 全文大小:999 KB
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  • 作者单位:Yan-Hong Li (1)
    Yan-Xia Bai (1)
    Chun-Mei Pan (2)
    Wei-Wei Li (1)
    Hui-Qin Zheng (1)
    Jing-Nan Zhang (1)
    Yao-Ting Fan (1)
    Hong-Wei Hou (1)

    1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450052, People’s Republic of China
    2. Biotechnology Department, Henan University of Animal Husbandry and Economy, Zhengzhou, 450011, People’s Republic of China
  • 刊物类别:Earth and Environmental Science
  • 刊物主题:Environment
    Environment
    Atmospheric Protection, Air Quality Control and Air Pollution
    Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
    Industrial Pollution Prevention
  • 出版者:Springer Berlin / Heidelberg
  • ISSN:1614-7499
文摘
The enhanced H2 production from maize straw had been achieved through the two-stage process of integrating H2 fermentation and microbial electrolysis cells (MECs) in the present work. Several key parameters affecting hydrolysis of maize straw through subcritical H2O were optimized by orthogonal design for saccharification of maize straw followed by H2 production through H2 fermentation. The maximum reducing sugar (RS) content of maize straw reached 469.7 mg/g-TS under the optimal hydrolysis condition with subcritical H2O combining with dilute HCl of 0.3 % at 230 °C. The maximum H2 yield, H2 production rate, and H2 content was 115.1 mL/g-TVS, 2.6 mL/g-TVS/h, and 48.9 % by H2 fermentation, respectively. In addition, the effluent from H2 fermentation was used as feedstock of MECs for additional H2 production. The maximum H2 yield of 1060 mL/g-COD appeared at an applied voltage of 0.8 V, and total COD removal reached about 35 %. The overall H2 yield from maize straw reached 318.5 mL/g-TVS through two-stage processes. The structural characterization of maize straw was also carefully investigated by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) spectra.

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