A Kinetics and Morphological Study on the Oxidation Behavior of Ti-Al-V Alloy

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• 作者：Faraz Omidbakhsh ; Ali Reza Ebrahimi ; Jaroslav Sojka
• 关键词：Oxidation ; Kinetics ; Activation energy ; Diffusion ; Titanium
• 刊名：Oxidation of Metals
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：84
• 期：1-2
• 页码：33-44
• 全文大小：1,506 KB
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• 作者单位：Faraz Omidbakhsh (1)
  Ali Reza Ebrahimi (2)
  Jaroslav Sojka (3)
  
  1. Department of Mechanical Engineering, Islamic Azad University, Tabriz Branch, P.O. Box 5157944533, Tabriz, Iran
  2. Mining and Metallurgical Engineering Department, Amirkabir University of Technology, Tehran, Iran
  3. Faculty of Metallurgy and Materials Engineering, Technical University of Ostrava (VSB), Ostrava, Czech Republic
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Tribology, Corrosion and Coatings
  Metallic Materials
  
• 出版者：Springer Netherlands
• ISSN：1573-4889

文摘

Oxidation behavior of Ti-Al-V alloy in air was studied by isothermal thermogravimetry. It was found that the oxidation?kinetics are parabolic in the temperature range 450-00?°C. The activation energies for reaction of titanium with oxygen and oxide growth were calculated as 90 and 114?kJ/mol, respectively. Microhardness measurements showed that thermal oxidation at 700?°C could increase the depth of subsurface diffusion zone up to 150?μm. The morphological studies of oxidized surfaces revealed that the thermal oxidation at 700?°C led to scaling and eventual detachment of the scale from the substrate due to the cracking at the metal/oxide interface.