Excess parameters for the binary mixtures of sulfolane with chloroethanes at different temperatures

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• 作者：Noothi Raghuram ; Ryshetti Suresh…
• 关键词：Sulfolane ; Chloroethanes ; Binary mixtures ; Excess parameters ; Molecular interactions
• 刊名：Journal of Thermal Analysis and Calorimetry
• 出版年：2015
• 出版时间：March 2015
• 年：2015
• 卷：119
• 期：3
• 页码：2107-2117
• 全文大小：495 KB
• 参考文献：1. Rathanam, MV, Sudhir, M, Kumar, MS (2010) Densities, viscosities, and refractive indices of binary mixtures of diethyl oxalate with some ketones at (303.15, 308.15, and 313.15) K. J Chem Eng Data 55: pp. 5946-5952 CrossRef
  2. Hasan, M, Shirude, DF, Hiray, AP, Kadam, UB, Sawant, AB (2006) Measurement and correlation of the excess properties of ternary mixture of x1[hmim][bf4]?+?x21-propanol?+?x32-propanol at different temperatures. J Chem Eng Data 51: pp. 1922-1926 CrossRef
  3. Radhamma, M, Venkatesu, P, Rao, MVP (2008) Excess molar volumes and ultrasonic studies of dimethylsulphoxide with ketones at T?=?303.15?K. J Chem Thermodyn. 40: pp. 492-497 CrossRef
  4. Venkatramana, L, Gardas, RL, Sivakumar, K, Reddy, KD (2014) Thermodynamics of binary mixtures: the effect of substituents in aromatics on their excess properties with benzylalcohol. Fluid Phase Equilib 367: pp. 7-21 CrossRef
  5. Shymala, V, Shivakumar, VK, Venkateshwarlu, P (2006) Excess molar volumes and ultrasonic studies of dimethylsulphoxide with ketones at T?=?303.15?K. J Chem Thermodyn. 38: pp. 1553-1562 CrossRef
  6. Venkatesu, P, Rao, MVP (1997) Excess volumes of N, N-dimethylformamide?+?cyclohexanone?+?1-alkanols at 303.15?K. J Chem Eng Data 42: pp. 90-92 CrossRef
  7. Changsheng, Y, Peisheng, MA, Qing, Z (2004) Excess molar volumes and viscosities of binary mixtures of sulfolane with benzene, toluene, ethylbenzene, p-xylene, o-xylene, and m-xylene at 303.15 and 323.15?K and atmospheric pressure. J Chem Eng Data 49: pp. 881-885 CrossRef
  8. Syeda, AB, Koppula, AJ, Boodida, S, Nallani, S (2010) Excess molar volumes and sound speed in (phenylacetonitrile?+?1,2-dichloroethane), (phenylacetonitrile?+?1,1,2-trichloroethane), (phenylacetonitrile?+?1,1,2,2-tetrachloroethane), (phenylacetonitrile?+?trichloroethene), and (phenylacetonitrile?+?tetrachloroethene) at temperatures of (303.15, 308.15, and 313.15) K. J Chem Eng Data 55: pp. 1405-1410 CrossRef
  9. Tangeda, SJ, Satyanarayana, N (2005) Ultrasonic studies of binary mixtures of some aromatic ketones with N-methyl-acetamide at 308.15 K. J Chem Eng Data 50: pp. 89-91 CrossRef
  10. Tangeda, SJ, Satyanarayana, N (2006) Density and viscosity of binary liquid systems of N-methylacetamide with aromatic ketones at T?=?308.15 K. J Chem Thermodyn. 38: pp. 272-277 CrossRef
  11. Satyanarayna, B, Tangeda, SJ, Satyanarayana, N (2006) Ultrasonic studies on binary mixtures of some aromatic ketones with acetonitrile at T?=?308.15 K. J Chem Thermodyn. 38: pp. 1438-1442 CrossRef
  12. Ranjith, KB, Murali, KP, Satyanarayana, B, Tangeda, SJ, Satyanarayana, N (2008) Densities, Viscosities and speed of sound of binary mixtures of phenylacetonitrile with some aliphatic alcohols at 308.15 K. Indian J Chem 47A: pp. 1026-1031
  13. Satyanarayna, B, Kumar, BR, Tangeda, SJ, Satyanarayana, N (2007) Densities and viscosities of binary liquid mixtures of N-methylacetamide with some chloroethanes and chloroethenes at T?=?308.15 K. J Chem Thermodyn. 39: pp. 16-21 CrossRef
  14. Satyanarayana, N, Satyanarayna, B, Tangeda, SJ (2007) Density and speed of sound of binary mixtures of N-methylacetamide with ethyl acetate, ethyl chloroacetate, and ethyl cyanoacetate in the temperature interval (303.15-18.15) K. J Chem Eng Data 52: pp. 405-409 CrossRef
  15. Kumar, BR, Satyanarayna, B, Asra, BS, Jyothi, KA, Tangeda, SJ, Satyanarayana, N (2009) Volumetric and transport properties of
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Sciences
  Polymer Sciences
  Physical Chemistry
  Inorganic Chemistry
  Measurement Science and Instrumentation
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1572-8943

文摘

Densities (ρ), viscosities (η) and ultrasonic velocities (u) have been measured for the binary mixtures of sulfolane with 1,2-dichloroethane, 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane over the entire range of mole fraction at T?=?(303.15, 308.15 and 313.15) K. These data have been used to compute the excess molar volume (V E), deviation in viscosity (Δη), deviation in isentropic compressibility (Δκs), excess Gibbs free energy of activation of viscous flow (G *E) and Grunberg–Nissan interaction parameter ( \( d^{\prime } \) ). The excess parameters have been fitted to Redlich–Kister-type polynomial equation using multiparametric nonlinear regression analysis to estimate the binary coefficients and standard deviation. The experimental results have been discussed in terms of dipole–dipole interactions and formation of molecular complexes between unlike molecules of the investigated mixtures. Furthermore, the effect of temperature and chlorine atoms of chloroethane is also studied for the present binary mixtures.