Electrochemical properties of Co-less layered transition metal oxide as high energy cathode material for Li-ion batteries

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• 作者：Sungho Choo (1) (4)
  Hye Yeon Kim (1)
  Dong Young Yoon (1)
  Wonchang Choi (1)
  Si-Hyung Oh (1)
  Jeh Beck Ju (2)
  Jang Myoun Ko (3)
  Ho Jang (4)
  Won Il Cho (1)
  
• 关键词：Li Ion Battery ; High Capacity ; Cathode ; Nickel Manganese Oxide ; Solid State Method ; Co ; precipitation
• 刊名：Korean Journal of Chemical Engineering
• 出版年：2014
• 出版时间：May 2014
• 年：2014
• 卷：31
• 期：5
• 页码：905-910
• 全文大小：
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• 作者单位：Sungho Choo (1) (4)
  Hye Yeon Kim (1)
  Dong Young Yoon (1)
  Wonchang Choi (1)
  Si-Hyung Oh (1)
  Jeh Beck Ju (2)
  Jang Myoun Ko (3)
  Ho Jang (4)
  Won Il Cho (1)
  
  1. Center for Energy Convergence, Korea Institute of Science and Technology, Seoul, 136-791, Korea
  4. Department of Materials Science and Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul, 136-701, Korea
  2. Department of Chemical Engineering, Hongik University, Seoul, 121-791, Korea
  3. Department of Chemical and Biological Engineering, Hanbat National University, 125, Yuseong-gu, Daejeon, 305-719, Korea
  
• ISSN：1975-7220

文摘

High energy nickel manganese cobalt oxide materials (HENMC) are one of the most viable cathode materials for a high energy density lithium ion battery (LIB), but they contain expensive and toxic cobalt (Co). We synthesized Co-free high energy nickel manganese oxide cathode materials (HENM) via a solid state reaction method and a coprecipitation method. Their structural and electrochemical properties were comparatively investigated using X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), inductively coupled plasma (ICP), electron probe micro-analysis (EPMA), particle size analysis (PSA) and electrochemical impedance spectroscopy (EIS). The co-precipitated HENM and the solid state fabricated HENM showed high capacities of 250 mAhg? and 240 mAhg?, respectively. It suggests that the solid state fabricated method of HENM would be a good candidate for practical application as well as the co-precipitated one.