Red and yellow ochres from the archaeological site Pedra do Cantagalo I, in Piripiri, Piauí, Brazil
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- 作者：Luis Carlos Duarte Cavalcante…
- 关键词：Prehistoric pigment ; Hematite ; Goethite ; Mössbauer spectroscopy ; Archaeometry
- 刊名：Hyperfine Interactions
- 出版年：2017
- 出版时间：November 2017
- 年：2017
- 卷：238
- 期：1
- 全文大小：
- 刊物类别：Physics and Astronomy
- 刊物主题：Nuclear Physics, Heavy Ions, Hadrons; Atomic, Molecular, Optical and Plasma Physics; Condensed Matter Physics; Surfaces and Interfaces, Thin Films;
- 出版者：Springer International Publishing
- ISSN：1572-9540
- 卷排序：238
文摘
The archaeological site Pedra do Cantagalo I is a sandstone shelter displaying rupestrian inscriptions. It is located in the rural area of the municipality of Piripiri, in the northern region of the Piauí state, Brazil. The site was found as being originally decorated with more than 1,900 prehistoric rupestrian paintings, along with engravings, lithics, ceramic fragments and mineral pigments forming reddish and yellowish ochres. Materials of these ochres, collected from recent excavations in this archaeological site, were analyzed by energy dispersive X-ray fluorescence (EDXRF); backscattering and transmission 57Fe-Mössbauer spectroscopy at 298 K and 25 K and powder X-ray diffraction (XRD), in an effort to assess the chemical and mineralogical characteristics of these sources of pigments that composed the ancient paint materials of the site. The iron contents (expressed as Fe 2O3) for the reddish ochres were found to range from ∼60 to ∼68 mass%; for the yellowish ochres the corresponding content was ∼34 mass%, as determined by EDXRF. From the Mössbauer spectra for these red ochre samples, hematite (αFe 2O3) or a mixture of hematite and goethite (αFeOOH) were identified. Actually, the spectra at room temperature for the yellow ochres are rather complex, as it is usual for most soil clay materials. At least part of the intense central doublet was assumed to be from superparamagnetic iron oxides in very small particles. The Mössbauer patterns at 25 K allowed confirming this assumption, as the superparamagnetic relaxation effects were virtually suppressed; the spectral contributions due to goethite could be thus more easily separated.